Stereoselective synthesis of 1,4-dienes through sequential cross coupling of (E)-α-selanylvinylstannanes

被引:7
|
作者
Ma, Y [1 ]
Huang, X [1 ]
机构
[1] Hangzhou Univ, Dept Chem, Hangzhou 310028, Peoples R China
来源
关键词
D O I
10.1039/a800580j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(E)-alpha-Selanylvinylstannanes underwent palladium-catalysed coupling reaction with allyl bromides to give 1,4-dienyl selenides; the products can react with Grignard reagent to afford 1,4-dienes in the presence of Ni(dppp)(2)Cl-2.
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页码:312 / +
页数:2
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