A simple and efficient method to prepare graphene by reduction of graphite oxide with sodium hydrosulfite

被引:190
作者
Zhou, Tiannan [1 ]
Chen, Feng [1 ]
Liu, Kai [1 ]
Deng, Hua [1 ]
Zhang, Qin [1 ]
Feng, Jiwen [2 ]
Fu, Qiang [1 ]
机构
[1] Sichuan Univ, Coll Polymer Sci & Engn, State Key Lab Polymer Mat Engn, Chengdu 610065, Peoples R China
[2] Chinese Acad Sci, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Inst Phys & Math, Wuhan 430071, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1088/0957-4484/22/4/045704
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Inspired by an ancient reducing method used in textile production, sodium hydrosulfite was used to reduce graphite oxide as an efficient reducing agent in our work. The reduced materials were characterized by x-ray photoelectron spectroscopy, thermogravimetric analysis, wide-angle x-ray scattering, Raman spectroscopy, solid state C-13 NMR spectroscopy and electrical conductivity measurements, respectively. The results showed that graphite oxide can be reduced with sodium hydrosulfite in a few minutes, with a degree of reduction comparable to those achieved with hydrazine. It provides an efficient method to reduce graphite oxide and could be used as a method to prepare novel composites.
引用
收藏
页数:6
相关论文
共 20 条
[1]   Evaluation of solution-processed reduced graphene oxide films as transparent conductors [J].
Becerril, Hdctor A. ;
Mao, Jie ;
Liu, Zunfeng ;
Stoltenberg, Randall M. ;
Bao, Zhenan ;
Chen, Yongsheng .
ACS NANO, 2008, 2 (03) :463-470
[2]   Electromechanical resonators from graphene sheets [J].
Bunch, J. Scott ;
van der Zande, Arend M. ;
Verbridge, Scott S. ;
Frank, Ian W. ;
Tanenbaum, David M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
SCIENCE, 2007, 315 (5811) :490-493
[3]   Preparation and characterization of graphene oxide paper [J].
Dikin, Dmitriy A. ;
Stankovich, Sasha ;
Zimney, Eric J. ;
Piner, Richard D. ;
Dommett, Geoffrey H. B. ;
Evmenenko, Guennadi ;
Nguyen, SonBinh T. ;
Ruoff, Rodney S. .
NATURE, 2007, 448 (7152) :457-460
[4]   Graphene-based Composite Thin Films for Electronics [J].
Eda, Goki ;
Chhowalla, Manish .
NANO LETTERS, 2009, 9 (02) :814-818
[5]   Deoxygenation of Exfoliated Graphite Oxide under Alkaline Conditions: A Green Route to Graphene Preparation [J].
Fan, Xiaobin ;
Peng, Wenchao ;
Li, Yang ;
Li, Xianyu ;
Wang, Shulan ;
Zhang, Guoliang ;
Zhang, Fengbao .
ADVANCED MATERIALS, 2008, 20 (23) :4490-4493
[6]   Practical Chemical Sensors from Chemically Derived Graphene [J].
Fowler, Jesse D. ;
Allen, Matthew J. ;
Tung, Vincent C. ;
Yang, Yang ;
Kaner, Richard B. ;
Weiller, Bruce H. .
ACS NANO, 2009, 3 (02) :301-306
[7]   Environment-Friendly Method To Produce Graphene That Employs Vitamin C and Amino Acid [J].
Gao, Jian ;
Liu, Fang ;
Liu, Yiliu ;
Ma, Ning ;
Wang, Zhiqiang ;
Zhang, Xi .
CHEMISTRY OF MATERIALS, 2010, 22 (07) :2213-2218
[8]   Electronic transport properties of individual chemically reduced graphene oxide sheets [J].
Gomez-Navarro, Cristina ;
Weitz, R. Thomas ;
Bittner, Alexander M. ;
Scolari, Matteo ;
Mews, Alf ;
Burghard, Marko ;
Kern, Klaus .
NANO LETTERS, 2007, 7 (11) :3499-3503
[9]   PREPARATION OF GRAPHITIC OXIDE [J].
HUMMERS, WS ;
OFFEMAN, RE .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (06) :1339-1339
[10]   Synthesis of poly(vinyl alcohol)/reduced graphite oxide nanocomposites with improved thermal and electrical properties [J].
Javier Salavagione, Horacio ;
Martinez, Gerardo ;
Gomez, Marian A. .
JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (28) :5027-5032