Recent progress on covalent organic framework materials as CO2 reduction electrocatalysts

被引:17
作者
Fan, Yang [1 ,2 ]
Chen, Mengyin [3 ]
Xu, Naizhang [3 ]
Wang, Kaiqiang [3 ]
Gao, Qiang [1 ]
Liang, Jing [1 ]
Liu, Yubing [1 ,3 ]
机构
[1] Nanjing Polytech Inst, Environm Engn Coll, Jiangsu Engn & Technol Res Ctr VOCs Treatment, Nanjing, JS, Peoples R China
[2] Shenzhen Univ, Inst Microscale Optoelect, Int Collaborat Lab Mat Optoelect Sci 2D, Technol Minist Educ, Shenzhen, Peoples R China
[3] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Mesoscop Chem MOE, Jiangsu Prov Key Lab Vehicle Emiss Control, Nanjing, Peoples R China
来源
FRONTIERS IN CHEMISTRY | 2022年 / 10卷
基金
中国国家自然科学基金;
关键词
CO2; reduction; electrocatalysts; carbon neutralization; sustainability; COFs; CARBON-DIOXIDE; ACTIVE-SITES; ELECTROREDUCTION; CATALYSTS; OPPORTUNITIES; CRYSTALLINE; CONVERSION;
D O I
10.3389/fchem.2022.942492
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
CO2 emission caused by fuel combustion and human activity has caused severe climate change and other subsequent pollutions around the world. Carbon neutralization via various novel technologies to alleviate the CO2 level in the atmosphere has thus become one of the major topics in modern research field. These advanced technologies cover CO2 capture, storage and conversion, etc., and electrocatalytic CO2 reduction reaction (CO2RR) by heterogeneous catalysts is among the most promising methods since it could utilize renewable energy and generate valuable fuels and chemicals. Covalent organic frameworks (COFs) represent crystalline organic polymers with highly rigid, conjugated structures and tunable porosity, which exhibit significant potential as heterogeneous electrocatalysts for CO2RR. This review briefly introduces related pioneering works in COF-based materials for electrocatalytic CO2RR in recent years and provides a basis for future design and synthesis of highly active and selective COF-based electrocatalysts in this direction.
引用
收藏
页数:8
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