Temperature dependence of chemical and biophysical rate processes: Phenomenological approach to deviations from Arrhenius law

被引：144

作者：

Aquilanti, Vincenzo ^{[2
]}

Mundim, Kleber Carlos ^{[1
,2
]}

Elango, Munusamy ^{[2
]}

Kleijn, Steven ^{[3
]}

Kasai, Toshio ^{[4
]}

机构：

[1] Univ Brasilia, Inst Quim, BR-70904970 Brasilia, DF, Brazil

[2] Univ Perugia, Dipartimento Chim, I-06123 Perugia, Italy

[3] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

[4] Osaka Univ, Grad Sch Sci, Dept Chem, Osaka 5600043, Japan

来源：

CHEMICAL PHYSICS LETTERS | 2010年 / 498卷 / 1-3期

关键词：

TRANSITION-STATE THEORY; MYOSIN SUBFRAGMENT-1; MYCOPLASMA-MOBILE; ACTIVATION-ENERGY; VELOCITY; FORCE; OPTIMIZATION; STATISTICS;

D O I：

10.1016/j.cplett.2010.08.035

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Arrhenius plots, which are used to represent the effects of temperature on the rates of chemical and biophysical processes and on various transport phenomena in materials science, may exhibit deviations from linearity. Account of curvature is provided here by a formula which involves a deformation of the exponential function, of the kind recently encountered in treatments of non-extensivity in statistical mechanics. We present here examples on diverse topics - respiration rates of plants, speed of gliding of bacteria, quantum mechanical tunneling in a chemical reaction - illustrating the variety of possible applications and the additional insight that can be gained. (C) 2010 Elsevier B. V. All rights reserved.

引用

页码：209 / 213

页数：5

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