A facile approach to the synthesis of Er3+-Yb3+-Mo6+ co-doped TiO2/Yb2Ti2O7 electrospun nanofibers and high thermal sensitivity

被引:1
作者
Liu, Kuichao [1 ,2 ]
Ma, Ke [1 ]
Tao, Hualong [1 ]
Cui, Yan [1 ]
Tian, Xingjian [1 ]
Liu, Shimin [1 ]
He, Ming [2 ]
Dong, Bin [2 ]
Song, Bo [3 ]
Zhang, Zhihua [1 ]
机构
[1] Dalian Jiaotong Univ, Sch Mat Sci & Engn, Dalian 116028, Peoples R China
[2] Dalian Minzu Univ, Sch Phys & Mat Engn, Key Lab Photosensit Mat & Devices Liaoning Prov, Key Lab New Energy & Rare Earth Resource Utilizat, Dalian 116600, Peoples R China
[3] Harbin Inst Technol, Acad Fundamental & Interdisciplinary Sci, Harbin 150080, Peoples R China
基金
中国国家自然科学基金;
关键词
Optical temperature sensing; Er3+-Yb3+-Mo6+ co-doped TiO2/Yb2Ti2O7; Nanofibers; Up-conversion emission; Fluorescence intensity ratio; UP-CONVERSION EMISSIONS; LUMINESCENCE PROPERTIES; SELECTIVE ENHANCEMENT; GREEN; SENSORS;
D O I
10.1007/s10971-021-05598-8
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Er3+-Yb3+-Mo6+ co-doped TiO2/Yb2Ti2O7 up-conversion luminescent nanofibers have been successfully synthesized using the electrospinning technology followed by thermolysis. The effects of the precursor ratio and annealing process on up-conversion luminescent character were investigated. The phase of TiO2 was determined to be either anatase or rutile. And the cubic Yb2Ti2O7 in Er3+-Yb3+-Mo6+ co-doped TiO2 phosphor was confirmed. After annealing at high temperature, the up-conversion luminescent intensity of the studied system increased obviously. The fluorescence intensity ratio (FIR) used to be made on the basis of green up-conversion emissions. It was studied as a function of temperature. The maximum rate of sensitivity was similar to 0.01 K-1 in the range of 300-600 K. The results indicate that Er3+-Yb3+-Mo6+ co-doped TiO2/Yb2Ti2O7 phosphor is a brand-new material that meets the requirement of the optical temperature sensing.
引用
收藏
页码:557 / 564
页数:8
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