The synthesis of phenyl carbamates catalyzed by iron (II) bromide: An oxidative approach for cross-coupling of phenols with formamides

被引：1

作者：

Vala, Manoj Kumar ^{[1
,2
]}

Sudhakar, Chithaluri ^{[1
]}

Adurthi, Suryakumari ^{[1
,2
]}

Vanam, Shekhar ^{[3
]}

机构：

[1] GITAM Deemed Univ, Dept Chem, Hyderabad, India

[2] TARA Govt Degree Coll, Dept Chem, Sangareddy, India

[3] KRR Govt Degree Coll, Dept Chem, Kodad, Telangana, India

来源：

SYNTHETIC COMMUNICATIONS | 2022年 / 52卷 / 02期

关键词：

CDC reaction; formamide; iron (II) bromide; oxidation; 1; 10-phenanthroline; phenyl carbamate; DIRECT AMIDATION; AMINES; EFFICIENT; ALCOHOLS; CARBONYLATION; SUBSTITUTION; ACTIVATION; ROUTE; UREAS; MILD;

D O I：

10.1080/00397911.2021.2017459

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbamate group is a key structural motif in many approved drugs and pro-drugs. There is increasing use of carbamates in the medicinal chemistry and agrochemical industry. We present, reagents and chemical methodologies for the synthesis of carbamates, and recent applications. The direct coupling of simple phenols with mono- and di-alkyl formamides provided the phenylcarbamate products.

引用

页码：250 / 257

页数：8

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