Adsorbate induced reconstruction of cobalt surfaces

被引：91

作者：

Ciobica, I. M. ^{[1
]}

van Santen, R. A. ^{[2
]}

van Berge, P. J. ^{[3
]}

de Loosdrecht, J. van ^{[3
]}

机构：

[1] Eindhoven Univ Technol, Sasol Technol Netherlands BV, NL-5600 MB Eindhoven, Netherlands

[2] Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands

[3] Sasol Technol Pty Ltd, ZA-1947 Sasolburg, South Africa

来源：

SURFACE SCIENCE | 2008年 / 602卷 / 01期

关键词：

chemisorption; surface reconstruction; FCC-cobalt surfaces;

D O I：

10.1016/j.susc.2007.09.060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Coverage dependence adsorption of intermediates typical for syngas conversion is studied theoretically on FCC-cobalt surfaces. The FCC structure is relevant for cobalt particles active in this reaction. Emphasis on the analysis is on the thermodynamics of surface reconstruction as a function of surface adsorbate and surface coverage. An important result is the finding that only adsorbed carbon induced reconstruction of FCC-CO(1 1 1) to FCC-CO(1 0 0) as well as the clock reconstruction for the two surfaces. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：17 / 27

页数：11

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