Adsorption of mercury from aqueous solution on synthetic polydopamine nanocomposite based on magnetic nanoparticles using Box-Behnken design

被引:39
作者
Davodi, Behzad [1 ]
Ghorbani, Mohsen [2 ]
Jahangiri, Mansour [1 ]
机构
[1] Semnan Univ, Fac Chem Engn Gas & Petr, Semnan, Iran
[2] Babol Noshirvani Univ Technol, Dept Chem Engn, Shariati Ave, Babol Sar, Iran
关键词
Mercury; Nanocomposite; Adsorption; RSM; Box-Behnken design; Optimization; WALLED CARBON NANOTUBES; HEAVY-METAL IONS; FE3O4; NANOPARTICLES; SEPARATION PROCESS; ACTIVATED CARBON; WASTE-WATER; REMOVAL; SORPTION; HG(II); OPTIMIZATION;
D O I
10.1016/j.jtice.2017.07.024
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The aim of this study is to examine the possibility of using synthesized functional polydopamine@Fe3O4 nanocomposite (PDA@Fe3O4) with magnetic response and a special surface area as the most effective adsorbent to remove the mercury (Hg(II)) from aqueous solution in batch process (in batch mode/ in batch phase/ in bath processing/ in a batch process). The structural characterization of this nanocomposite was performed by XRD, TEM, TGA and FTIR analyses. Response surface methodology was used to optimize the Hg(II) adsorption capacity mg/g with three experimental factors using Box-Behnken design (BBD). The optimum conditions included: pH 5.36, Hg(II) initial concentration 98.65 mg/g, contact time 5.17 h. The maximum adsorption capacity of Hg(II) in batch administrations was 307 mg/g. (C) 2017 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:363 / 378
页数:16
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