δ and α SP3 C-H bond oxidation of Sulfonamides with PhI(OAc)2/I2 under metal-free conditions

被引：141
作者：
Fan, Renhua
Pu, Dongming
Wen, Fengqi
Wu, Jie
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 23期
关键词：
D O I：
10.1021/jo7016982
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] An efficient delta and alpha sp(3) C-H bond oxidation of sulfonamides with PhI(OAc)(2)/I-2 under metal-free conditions has been reported. The reaction provides a useful route to pyrrolidines, N-sulfonylimines, and various sulfonamide derivatives. The potential of this reaction system can be evaluated by its mild condition and simple process.
引用
收藏
页码：8994 / 8997
页数：4
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