Two types of new polymeric silver(I) complexes from 1,4-thioxane and silver triflate

被引：15

作者：

Buchholz, HA ^{[1
]}

Prakash, GKS ^{[1
]}

Vaughan, JFS ^{[1
]}

Bau, R ^{[1
]}

Olah, GA ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90089

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 13期

关键词：

D O I：

10.1021/ic960123d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,4-Thioxane and silver triflate form two distinct ionic polymers comprising of tetracoordinate silver(I) cations. In both cases, silver is coordinated by the sulfur atoms of two 1.4-thioxane molecules and by the oxygen atoms of two triflate ions. In structure 1, bridging between Ag+ centers occurs only via the triflate moieties. Structure 2 also contains bridges through the second nonbonded electron pair of the sulfur ligands to give an infinite two-dimensional polymer in the crystal.

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页码：4076 / &

页数：3

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