Development of novel and efficient synthesis of group 14 element (Ge and Sn) catenates by use of samarium (II) diiodide

被引：24

作者：

Azemi, T ^{[1
]}

Yokoyama, Y ^{[1
]}

Mochida, K ^{[1
]}

机构：

[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 06期

关键词：

group; 14; elements; catenates; samarium (II) diiodide;

D O I：

10.1016/j.jorganchem.2004.12.032

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Group 14 element catenates such as di-, tri-, poly-germanes, and polystannanes are efficiently synthesized by use of the one-electron reducing agent Sml(2) under mild homogeneous conditions in good yields. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1588 / 1593

页数：6

共 45 条

[21]

KUMADA M, 1974, J ORGANOMET CHEM, V17, P1309

[22] SOLUBLE ALKYL SUBSTITUTED POLYGERMANES - THERMOCHROMIC BEHAVIOR [J].

MILLER, RD ;

SOORIYAKUMARAN, R .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1987, 25 (01) :111-125

[23] POLYSILANE HIGH POLYMERS [J].

MILLER, RD ;

MICHL, J .

CHEMICAL REVIEWS, 1989, 89 (06) :1359-1410

[24]

Mochida K, 1997, APPL ORGANOMET CHEM, V11, P949

[25] Nonlinear optical susceptibility of oligo- and polygermanes [J].

Mochida, K ;

Nagano, S ;

Maeyama, S ;

Kodaira, T ;

Watanabe, A ;

Ito, O ;

Matsuda, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1997, 70 (03) :713-716

[26] HE-I PHOTOELECTRON-SPECTRA OF PERMETHYLATED POLYGERMANES [J].

MOCHIDA, K ;

MASUDA, S ;

HARADA, Y .

CHEMISTRY LETTERS, 1992, (12) :2281-2284

[27] LASER FLASH-PHOTOLYSIS OF POLYGERMANES - GENERATION OF GERMYLENES AND POLYGERMYL RADICALS [J].

MOCHIDA, K ;

KIMIJIMA, K ;

CHIBA, H ;

WAKASA, M ;

HAYASHI, H .

ORGANOMETALLICS, 1994, 13 (02) :404-406

[28] PHOTOLYSIS OF PERMETHYLATED POLYGERMANES [J].

MOCHIDA, K ;

CHIBA, H ;

OKANO, M .

CHEMISTRY LETTERS, 1991, (01) :109-112

[29] SYNTHESIS, ABSORPTION CHARACTERISTICS AND SOME REACTIONS OF POLYGERMANES [J].

MOCHIDA, K ;

CHIBA, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 473 (1-2) :45-54

[30] CHARGE-TRANSFER SPECTRA OF PERMETHYLATED POLYGERMANES TCNE TO AFFORD 1-1 ADDUCTS [J].

MOCHIDA, K ;

HODOTA, C ;

HATA, R ;

FUKUZUMI, S .

ORGANOMETALLICS, 1993, 12 (02) :586-588

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