Development of novel and efficient synthesis of group 14 element (Ge and Sn) catenates by use of samarium (II) diiodide

被引:24
作者
Azemi, T [1 ]
Yokoyama, Y [1 ]
Mochida, K [1 ]
机构
[1] Gakushuin Univ, Fac Sci, Dept Chem, Toshima Ku, Tokyo 1718588, Japan
关键词
group; 14; elements; catenates; samarium (II) diiodide;
D O I
10.1016/j.jorganchem.2004.12.032
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Group 14 element catenates such as di-, tri-, poly-germanes, and polystannanes are efficiently synthesized by use of the one-electron reducing agent Sml(2) under mild homogeneous conditions in good yields. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1588 / 1593
页数:6
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