Characteristics of Low-Temperature Polyvinyl Chloride Carbonization by Catalytic CuAl Layered Double Hydroxide

被引:6
|
作者
Pang, Erwei [1 ]
Liu, Weijun [1 ]
Zhang, Shuhua [2 ]
Fu, Nengshuo [2 ]
Tian, Zhongxun [1 ]
机构
[1] Shanghai Univ Engn Sci, Sch Mech & Automot Engn, Shanghai 201620, Peoples R China
[2] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China
关键词
catalytic PVC pyrolysis; PVC carbonization; CuAl layered double hydroxide (CuAl-LDH); THERMAL-DEGRADATION; PVC; PYROLYSIS; WASTE; COPPER;
D O I
10.3390/pr8010120
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A good way to make carbon materials was presented in low-temperature polyvinyl chloride (PVC) carbonization by catalysis. The process of low-temperature PVC carbonization by CuAl-layered double hydroxide (CuAl-LDH) was investigated by thermogravimetric analysis (TGA) and tubular furnace. The results show that CuAl-LDH accounting for 5% of PVC mass enabled acceleration of the dehydrochlorination in PVC as soon as possible and maximized the yield of the PVC carbonized product. The vacuum with 0.08 MPa, 20 degrees C/min heating rate and 90 min carbonized maintenance time were optimal for PVC carbonization. Moreover, the best morphology and yield of the carbonized product was provided at a carbonization temperature of 300 degrees C.
引用
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页数:11
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