Recent progress on confinement of polysulfides through physical and chemical methods

被引:105
作者
Li, Sheng-Yi [1 ,2 ]
Wang, Wen-Peng [1 ,2 ]
Duan, Hui [1 ,2 ]
Guo, Yu-Guo [1 ,2 ]
机构
[1] Chinese Acad Sci, CAS Key Lab Mol Nanostruct & Nanotechnol, CAS Res Educ Ctr Excellence Mol Sci, Inst Chem, Beijing 100190, Peoples R China
[2] Univ Chinese Acad Sci, Sch Chem Sci, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
Lithium-sulfur batteries; Confinement of polysulfides; Physical structure design; Chemical bonding; Shuttle effect; LITHIUM-SULFUR BATTERIES; LI-S BATTERIES; METAL-ORGANIC FRAMEWORK; REDUCED GRAPHENE OXIDE; X-RAY-DIFFRACTION; CATHODE MATERIAL; CARBON NANOTUBES; ELECTROCHEMICAL PROPERTIES; POLYACRYLONITRILE CATHODE; COMPOSITE CATHODE;
D O I
10.1016/j.jechem.2018.04.014
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
With high theoretical energy density and the natural abundance of S, lithium-sulfur (Li-S) batteries are considered to be the promising next generation high-energy rechargeable energy storage devices. However, issues including electronical insulation of S, the lithium polysulfides (LiPSs) dissolution and the short cycle lifespan have prevented Li-S batteries from being practical applied. Feasible settlements of confining LiPSs to reduce the loss of active substances and improve the cycle stability include wrapping sulfur with compact layers, designing matrix with porous or hollow structures, adding adsorbents owning strong interaction with sulfur and inserting polysulfide barriers between cathodes and separators. This review categorizes them into physical and chemical confinements according to the influencing mechanism. With further discussion of their merits and flaws, synergy of the physical and chemical confinement is believed to be the feasible avenue that can guide Li-S batteries to the practical application. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
引用
收藏
页码:1555 / 1565
页数:11
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