Stability of gold(I) glycinate complexes in aqueous solution

被引：6

作者：

Mironov, I. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 05期

关键词：

Gold compounds - pH effects - Phase equilibria - Solutions - Substitution reactions;

D O I：

10.1134/S0036023607050233

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stepwise substitution equilibrium AuCl2- + iX(-) = AuCl2-X-i(i)- + iCl(-), beta(i), where X- is the glycinate ion (H2N - CH2 - COO-), i = 1 or 2, at 25 degrees C in an aqueous solution with I = 1.0 mol/L (NaCl) has been studied pH-metrically. The corresponding constants are log beta(1) = 3.60 +/- 0.10, and log beta(2) = 6.2 +/- 0.2.

引用

页码：791 / 792

页数：2