Helical carbon nanofibers prepared by pyrolysis of acetylene with a catalyst derived from the decomposition of copper tartrate

被引:87
作者
Qin, Y [1 ]
Zhang, ZK [1 ]
Cui, ZL [1 ]
机构
[1] Qingdao Univ Sci & Technol, Key Lab Nanomat, Qingdao 266042, Peoples R China
关键词
carbon fibers; pyrolysis; scanning electron microscopy; microstructure;
D O I
10.1016/S0008-6223(03)00435-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The helical carbon nanofibers prepared by the pyrolysis of acetylene were discussed. The reaction used catalyst precursors derived from the decomposition of copper tartrate. It was found that copper nanocrystals were extraordinarily effective for the growth of regularly coiled nanofibers under selected reaction conditions.
引用
收藏
页码:3072 / 3074
页数:3
相关论文
共 10 条
[1]   A FORMATION MECHANISM FOR CATALYTICALLY GROWN HELIX-SHAPED GRAPHITE NANOTUBES [J].
AMELINCKX, S ;
ZHANG, XB ;
BERNAERTS, D ;
ZHANG, XF ;
IVANOV, V ;
NAGY, JB .
SCIENCE, 1994, 265 (5172) :635-639
[2]   Three-dimensional vapor growth mechanism of carbon microcoils [J].
Chen, XQ ;
Saito, T ;
Kusunoki, M ;
Motojima, S .
JOURNAL OF MATERIALS RESEARCH, 1999, 14 (11) :4329-4336
[3]   Solid catalytic growth mechanism of micro-coiled carbon fibers [J].
Du, JH ;
Su, G ;
Bai, S ;
Sun, C ;
Cheng, HM .
SCIENCE IN CHINA SERIES E-TECHNOLOGICAL SCIENCES, 2001, 44 (04) :377-382
[4]   Kinetically controlled growth of helical and zigzag shapes of carbon nanotubes [J].
Gao, RP ;
Wang, ZL ;
Fan, SS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (06) :1227-1234
[5]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[6]   Three-dimensional growth mechanism of cosmo-mimetic carbon microcoils obtained by chemical vapor deposition [J].
Motojima, S ;
Chen, QQ .
JOURNAL OF APPLIED PHYSICS, 1999, 85 (07) :3919-3921
[7]   PREPARATION OF MICRO-COILED CARBON-FIBERS BY METAL POWDER-ACTIVATED PYROLYSIS OF ACETYLENE CONTAINING A SMALL AMOUNT OF SULFUR-COMPOUNDS [J].
MOTOJIMA, S ;
ITOH, Y ;
ASAKURA, S ;
IWANAGA, H .
JOURNAL OF MATERIALS SCIENCE, 1995, 30 (20) :5049-5055
[8]   Catalytic effects of metal carbides, oxides and Ni single crystal on the vapor growth of micro-coiled carbon fibers [J].
Motojima, S ;
Asakura, S ;
Kasemura, T ;
Takeuchi, S ;
Iwanaga, H .
CARBON, 1996, 34 (03) :289-296
[9]  
SU G, 2001, CHIN J MAT RES, V15, P623
[10]   Synthesis of regular coiled carbon nanotubes by Ni-catalyzed pyrolysis of acetylene and a growth mechanism analysis [J].
Wen, YK ;
Shen, ZM .
CARBON, 2001, 39 (15) :2369-2374