(2-Carboxyacetato-κ2O1,O1′)(rac-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N,N′,N",N′′′)nickel(II) perchlorate acetonitrile solvate

被引：1

作者：

Ou, Guang-Chuan ^{[2
]}

Ng, Seik Weng ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[2] Hunan Univ Sci & Engn, Dept Biol & Chem, Yongzhou 425100, Hunan, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

MONOHYDRATE;

D O I：

10.1107/S1600536810042637

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the crystal structure of the title salt, [Ni(C3H3O4)-(C16H36N4)]ClO4 center dot CH3CN, the macrocycle folds around the Ni-II atom, which is also chelated by the carboxylate monoanion. The geometry is a distorted NiN4O2 octahedron. The formula units are connected by N-H center dot center dot center dot O hydrogen bonds into centrosymmetric dimers. Further N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds link the complex molecules and the perchlorate ions.

引用

页码：M1468 / U1223

页数：11

共 8 条

[1]

Barbour L.J., 2001, J SUPRAMOL CHEM, V1, P189, DOI [DOI 10.1016/S1472-7862(02)00030-8, 10.1016/S1472-7862(02)00030-8]

[2]

*BRUK AXS INC, 2003, SAINT SMART

[3] Supramolecular Architectures of macrocyclic nickel(II) complexes with defined structures of cis and trans configurations [J].

Jiang, L ;

Feng, XL ;

Lu, TB .

CRYSTAL GROWTH & DESIGN, 2005, 5 (04) :1469-1475

[4] Bis(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N)(μ-L-malato-κ4O1,O2:O4,O4′)dinickel(II) bis(perchlorate) monohydrate [J].

Ou, Guang-Chuan ;

Zhou, Qiang ;

Ng, Seik Weng .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M728-U413

[5] (2-Carboxybenzoato-κ2O1,O1′)(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane-κ4N)nickel(II) perchlorate monohydrate [J].

Ou, Guang-Chuan ;

Zhang, Min ;

Yuan, Xian-You .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M726-U388

[6]

Sheldrick G.M., 1996, SADABS

[7] A short history of SHELX [J].

Sheldrick, George M. .

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 :112-122

[8] publCIF: software for editing, validating and formatting crystallographic information files [J].

Westrip, Simon P. .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 :920-925

← 1 →