Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

被引：34

作者：

Basuli, F

Bailey, BC

Huffman, JC

Mindiola, DJ ^{[1
]}

机构：

[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA

[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 13期

关键词：

D O I：

10.1039/b304633h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)(2) (Nacnac(-) = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)(2)C6H3)with AgOTf affords the cation [(Nacnac)Ti(NHAr)(2)][OTf] which is isolated and shown to gradually transform, by alpha-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac) Ti=NAr(OTf).

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收藏

页码：1554 / 1555

页数：2

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