Snapshots of an oxidatively induced α-hydrogen abstraction reaction to prepare a terminal and four-coordinate titanium imide

被引：34
作者：
Basuli, F
Bailey, BC
Huffman, JC
Mindiola, DJ [1 ]
机构：
[1] Indiana Univ, Dept Chem, Bloomington, IN 47405 USA
[2] Indiana Univ, Ctr Mol Struct, Bloomington, IN 47405 USA
来源：
CHEMICAL COMMUNICATIONS | 2003年 / 13期
关键词：
D O I：
10.1039/b304633h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
One electron oxidation of the bis-anilido titanium(III) complex (Nacnac)Ti(NHAr)(2) (Nacnac(-) = ArNC(CH3)CHC(CH3)NAr, Ar = 2,6-(CHMe2)(2)C6H3)with AgOTf affords the cation [(Nacnac)Ti(NHAr)(2)][OTf] which is isolated and shown to gradually transform, by alpha-hydrogen abstraction, to the terminal and four-coordinate titanium imide (Nacnac) Ti=NAr(OTf).
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收藏
页码：1554 / 1555
页数：2
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