Reversible transformation from amorphouse Na3Fe3(SO4)2(OH)6 to crystallized NaFe3(SO4)2(OH)6 Jarosite-type hydroxysulfate

被引：18
作者：
Gnanavel, M. [1 ]
Lebedev, O. I. [1 ]
Bazin, P. [2 ]
Raveau, B. [1 ]
Pralong, V. [1 ]
机构：
[1] Univ Caen, ENSICAEN, Lab Cristallog & Sci Mat CRISMAT, F-14050 Caen, France
[2] Univ Caen, CNRS, ENSICAEN, Lab Catalyse & Spectrochim, F-14050 Caen, France
来源：
SOLID STATE IONICS | 2015年 / 278卷
关键词：
Sodium iron hydroxysulfate; Na ion batteries; Cathode; NaFe3(SO4)(2)(OH)(6); NA-ION BATTERIES; LI-ION; ELECTRODE MATERIALS; SODIUM; SULFATE; LITHIUM; ELECTROCHEMISTRY; FE; CHEMISTRY; INSERTION;
D O I：
10.1016/j.ssi.2015.05.013
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An amorphous iron hydroxysulfate Na3Fe3(SO4)(2)(OH)(6) has been prepared for the first time from sodium insertion into the crystalline phase NaFe3(SO4)(2)(OH)(6). We show that this transformation is completely reversible, leading back to the well crystallized hexagonal phase on oxidation. This material could then be proposed as positive electrode material for Na ion batteries with a reversible capacity of 120 mAh/g at 2.72 V vs Na+/Na. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：38 / 42
页数：5
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  • [1] Krohnkite-Type Na2Fe(SO4)2•2H2O as a Novel 3.25 V Insertion Compound for Na-Ion Batteries
    Barpanda, Prabeer
    Oyama, Gosuke
    Ling, Chris D.
    Yamada, Atsuo
    [J]. CHEMISTRY OF MATERIALS, 2014, 26 (03) : 1297 - 1299
  • [2] Na2FeP2O7: A Safe Cathode for Rechargeable Sodium-ion Batteries
    Barpanda, Prabeer
    Liu, Guandong
    Ling, Chris D.
    Tamaru, Mao
    Avdeev, Maxim
    Chung, Sai-Cheong
    Yamada, Yuki
    Yamada, Atsuo
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (17) : 3480 - 3487
  • [3] Crystal chemistry of the natrojarosite-jarosite and natrojarosite-hydronium jarosite solid-solution series: A synthetic study with full Fe site occupancy
    Basciano, Laurel C.
    Peterson, Ronald C.
    [J]. AMERICAN MINERALOGIST, 2008, 93 (5-6) : 853 - 862
  • [4] Sodium and sodium-ion energy storage batteries
    Ellis, Brian L.
    Nazar, Linda F.
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2012, 16 (04) : 168 - 177
  • [5] Crystal Structure and Electrochemical Properties of A2MPO4F Fluorophosphates (A = Na, Li; M = Fe, Mn, Co, Ni)
    Ellis, Brian L.
    Makahnouk, W. R. Michael
    Rowan-Weetaluktuk, W. N.
    Ryan, D. H.
    Nazar, Linda F.
    [J]. CHEMISTRY OF MATERIALS, 2010, 22 (03) : 1059 - 1070
  • [6] Lithium Intercalation into the Jarosite-type Hydroxysulfate: A Topotactic Reversible Reaction from a Crystalline Phase to an Inorganic Polymer-like Structure
    Gnanavel, M.
    Pralong, V.
    Lebedev, O. I.
    Caignaert, V.
    Bazin, P.
    Raveau, B.
    [J]. CHEMISTRY OF MATERIALS, 2014, 26 (15) : 4521 - 4527
  • [7] Understanding the Electrochemical Mechanism of the New Iron-Based Mixed-Phosphate Na4Fe3(PO4)2(P2O7) in a Na Rechargeable Battery
    Kim, Hyungsub
    Park, Inchul
    Lee, Seongsu
    Kim, Hyunchul
    Park, Kyu-Young
    Park, Young-Uk
    Kim, Haegyeom
    Kim, Jongsoon
    Lim, Hee-Dae
    Yoon, Won-Sub
    Kang, Kisuk
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (18) : 3614 - 3622
  • [8] New Iron-Based Mixed-Polyanion Cathodes for Lithium and Sodium Rechargeable Batteries: Combined First Principles Calculations and Experimental Study
    Kim, Hyungsub
    Park, Inchul
    Seo, Dong-Hwa
    Lee, Seongsu
    Kim, Sung-Wook
    Kwon, Woo Jun
    Park, Young-Uk
    Kim, Chul Sung
    Jeon, Seokwoo
    Kang, Kisuk
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (25) : 10369 - 10372
  • [9] Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
    Kim, Sung-Wook
    Seo, Dong-Hwa
    Ma, Xiaohua
    Ceder, Gerbrand
    Kang, Kisuk
    [J]. ADVANCED ENERGY MATERIALS, 2012, 2 (07) : 710 - 721
  • [10] LITHIUM INSERTION INTO FE2(SO4)3 FRAMEWORKS
    MANTHIRAM, A
    GOODENOUGH, JB
    [J]. JOURNAL OF POWER SOURCES, 1989, 26 (3-4) : 403 - 408
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