Adsorption of chlorobenzene and benzene on γ-Al2O3

被引：5

作者：

Asnin, LD ^{[1
]}

Fedorov, AA ^{[1
]}

Chekryshkin, YS ^{[1
]}

机构：

[1] Russian Acad Sci, Ural Branch, Inst Tech Chem, Perm 614000, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2001年 / 50卷 / 01期

关键词：

adsorption; thermodynamics of adsorption; alumina; chlorobenzene; benzene;

D O I：

10.1023/A:1009573017700

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Adsorption of chlorobenzene and benzene on gamma -Al2O3 was investigated in the 413-572 K temperature region at an adsorbate partial pressure ranging from 2 to 1000 Pa. The adsorption isotherms were measured and the isosteric heats and the entropy characteristics of adsorption were determined. The experimentally found and theoretically calculated entropy changes upon adsorption were compared. The mobility of the molecules of both adsorbates in the adsorption layer was limited with respect to that predicted by the ideal two-dimensional gas model. The mechanism of adsorption of benzene and chlorobenzene is discussed.

引用

页码：68 / 72

页数：5

共 21 条

[1]

AKHNAZAROVA SL, 1978, OPTIMIZATSIYA EKSPER, P31

[2]

[Anonymous], 1983, TEORETICHESKIE OSNOV

[3]

Asnin LD, 2000, RUSS CHEM B+, V49, P178

[4] MESSUNG VON ADSORPTIONSISOTHERMEN AN KATALYSATOREN BEI HOHEN TEMPERATUREN MIT HILFE DER GAS-FESTKORPER-ELUIERUNGSCHROMATOGRAPHIE [J].

CREMER, E ;

HUBER, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1961, 73 (13) :461-&

[5] HIGH TEMPERATURE ADSORPTION STUDIES ON 13X MOLECULAR SIEVE AND OTHER POROUS SOLIDS BY PULSE FLOW TECHNIQUES [J].

EBERLY, PE .

JOURNAL OF PHYSICAL CHEMISTRY, 1961, 65 (01) :68-&

[6]

FEDOROV AA, 1998, ZH PRIKL KHIM, V71, P1828

[7]

Kiselev A. V., 1967, GAZOADSORBTSIONNAYA

[8]

KUBASOV AA, 1964, KINET KATAL, V5, P520

[9]

Lippens B. C, 1970, PHYSICAL CHEM ASPECT, P171

[10]

Lopatkin A.A., 1999, ZH FIZ KHIM, V73, P1769

← 1 2 3 →