A comparative investigation of uranium and thorium adsorption behavior on amidoximated copolymeric hydrogel

被引：15

作者：

Akl, Zeinab F. ^{[1
]}

机构：

[1] Egyptian Atom Energy Author, POB 11762, Cairo, Egypt

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2022年 / 331卷 / 04期

关键词：

Chelating polymers; gamma-Induced copolymerization; Uranium; Thorium; Recovery; SULFONIC-ACID; AQUEOUS-SOLUTION; REMOVAL; IONS; SORPTION; WASTE; U(VI);

D O I：

10.1007/s10967-022-08250-z

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

This work focuses on investigating the feasibility of using a crosslinked amidoximated copolymeric hydrogel as a potential adsorbent to recover uranium and thorium ions from aqueous media. The hydrogel was synthesized via gamma-irradiation copolymerization and characterized through FTIR, TGA, and SEM. The medium acidity notably affected the adsorption capacity of both ions. The adsorption data was in line with the pseudo-1st-order equation and the Freundlich isothermal model. The thermodynamics analysis showed that the temperature rise promoted the adsorption capacity. The reusability studies highlighted the good performance of the hydrogel up to five regeneration rounds.

引用

页码：1859 / 1867

页数：9

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