Carbide Evolution in High Molybdenum Nb-microalloyed H13 Steel during Annealing Process

被引:16
作者
Li, Tian-sheng [1 ,2 ]
Wang, Fu-ming [1 ]
Li, Chang-rong [3 ]
Zhang, Guo-qing [1 ]
Meng, Qing-yong [1 ]
机构
[1] Univ Sci & Technol Beijing, State Key Lab Adv Met, Beijing 100083, Peoples R China
[2] Hunan Inst Technol, Sch Mech Engn, Hengyang 421008, Hunan, Peoples R China
[3] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China
基金
国家高技术研究发展计划(863计划);
关键词
niobium microalloying; high molybdenum H13 steel; spheroidizing annealing; carbide; WORK TOOL STEEL; HOT; MICROSTRUCTURE; NIOBIUM;
D O I
10.1016/S1006-706X(15)30008-X
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
Based on the Thermo-Calc thermodynamic software, the type of equilibrium precipitated carbides and their contents in high Mo Nb-microalloyed H13 steel (NMH13 steel) were calculated. The composition, morphology, and distribution of carbides after spheroidal annealing of two forged experimental steels were comparatively examined by means of optical microscopy (OM), scanning electron microscopy (SEM), electron dispersive spectroscopy (EDS) and transmission electron microscopy (TEM). VC, M23C6 and M6C are identified in H13 steel after spheroidizing annealing, while (V, Nb)C, M23C6, M2C and M6C are observed in NMH13 steel. Moreover, it is found that the addition of Nb significantly enhances the stability of MC phase and the high Mo content accelerates the precipitation of small rod-shape M2C phase in NMH13 steel. The amount of the fine carbides in NMH13 steel obviously increased with M2C and M6C precipitated from the ferrite phase, which is in accordance with the results of thermodynamic calculations.
引用
收藏
页码:330 / 336
页数:7
相关论文
共 18 条
[1]   Complex carbide growth, dissolution, and coarsening in a modified 12 pct chromium steel -: an experimental and theoretical study [J].
Bjärbo, A ;
Hättestrand, M .
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE, 2001, 32 (01) :19-27
[2]  
[陈英伟 Chen Yingwei], 2010, [材料热处理学报, Transactions of Materials and Heat Treatment], V31, P75
[3]  
Cheng X. H., 2001, SHANGHAI METALS, V23, P1
[4]   Alloying design for high wear-resistant cast hot-forging die steels [J].
Cui Xiang-hong ;
Shan Jun ;
Yang Zi-run ;
Wei Min-xian ;
Wang Shu-qi ;
Dong Chuang .
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2008, 15 (04) :67-72
[5]  
Davenport A. T., 1975, Metal Science, V9, P201, DOI 10.1179/030634575790445044
[6]   Influence of silicon content on the precipitation of secondary carbides and fatigue properties of a 5%Cr tempered martensitic steel [J].
Delagnes, D ;
Lamesle, P ;
Mathon, MH ;
Mebarki, N ;
Levaillant, C .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2005, 394 (1-2) :435-444
[7]  
ELIAS CN, 1992, MATER SCI TECH SER, V8, P785, DOI 10.1179/026708392790171260
[8]  
[胡心彬 Hu Xinbin], 2004, [金属热处理, Heat treatment of metals], V29, P13
[9]   Effect of niobium on microstructure of cast AISI H13 hot work tool steel [J].
Kheirandish, Shahram ;
Noorian, Ahmad .
JOURNAL OF IRON AND STEEL RESEARCH INTERNATIONAL, 2008, 15 (04) :61-66
[10]  
[刘树勋 Liu Shuxun], 2002, [材料热处理学报, Transactions of materials and heat treatmient], V23, P15