Growth of TiO2 thin film by reactive RF magnetron sputtering using oxygen radical

被引:55
作者
Ogawa, H. [1 ]
Higuchi, T. [1 ]
Nakamura, A. [1 ]
Tokita, S. [1 ]
Miyazaki, D. [1 ]
Hattori, T. [1 ]
Tsukamoto, T. [1 ]
机构
[1] Tokyo Univ Sci, Dept Appl Phys, Tokyo 1628601, Japan
关键词
TiO2 thin film; rutile; anatase; RF magnetron sputtering; oxygen radical radiation;
D O I
10.1016/j.jallcom.2006.02.103
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
TiO2 thin films were deposited on MgO substrates by reactive RF magnetron sputtering using oxygen radicals. In order to perform the low temperature crystallization and control of crystal structure, the TiO2 thin film was irradiated by highly reactive oxygen radicals during the deposition. When the distance between the substrate and Ti-metal target (S-T distance) was 90 mm and substrate temperature were kept at 125 degrees C, the radical irradiated TiO2 film exhibited a (1 10) orientation with rutile structure. The radical irradiated TiO2 thin film prepared at 300 degrees C was changed from rutile to anatase structure by the adjustment of S-T distance. When the S-T distance was fixed at 110 mm, the TiO2 film exhibited a high a-axis orientation with anatase structure. The TiO2 rutile and anatase thin films consisted of small grains with very smooth surface. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:375 / 378
页数:4
相关论文
共 24 条
[1]  
Brady G.S., 1971, MAT HDB
[2]   Fabrication and characterization of anatase TiO2 thin film on glass substrate grown by pulsed laser deposition [J].
Choi, Y ;
Yamamoto, S ;
Umebayashi, T ;
Yoshikawa, A .
SOLID STATE IONICS, 2004, 172 (1-4) :105-108
[3]   ELECTROCHEMICAL EVIDENCE FOR THE MECHANISM OF THE PRIMARY STAGE OF PHOTOSYNTHESIS [J].
FUJISHIMA, A ;
HONDA, K .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1971, 44 (04) :1148-+
[4]   ELECTROCHEMICAL PHOTOLYSIS OF WATER AT A SEMICONDUCTOR ELECTRODE [J].
FUJISHIMA, A ;
HONDA, K .
NATURE, 1972, 238 (5358) :37-+
[5]  
Gusev VB, 1981, ZH PRIKL SPEKTROSK, V34, P939
[6]   LIGHT-INDUCED REDOX REACTIONS IN NANOCRYSTALLINE SYSTEMS [J].
HAGFELDT, A ;
GRATZEL, M .
CHEMICAL REVIEWS, 1995, 95 (01) :49-68
[7]   Electronic structure of p-type SrTiO3 by photoemission spectroscopy [J].
Higuchi, T ;
Tsukamoto, T ;
Sata, N ;
Ishigame, M ;
Tezuka, Y ;
Shin, S .
PHYSICAL REVIEW B, 1998, 57 (12) :6978-6983
[8]   Conductivity in transparent anatase TiO2 films epitaxially grown by reactive sputtering deposition [J].
Jeong, BS ;
Norton, DP ;
Budai, JD .
SOLID-STATE ELECTRONICS, 2003, 47 (12) :2275-2278
[9]   CONVERSION OF CARBOHYDRATE INTO HYDROGEN FUEL BY A PHOTOCATALYTIC PROCESS [J].
KAWAI, T ;
SAKATA, T .
NATURE, 1980, 286 (5772) :474-476
[10]   Postgrowth annealing effects of TiO2 thin films grown on InP substrate at low-temperature by metal-organic chemical-vapor deposition [J].
Kim, EK ;
Son, MH ;
Min, SK ;
Han, YK ;
Wang, CH ;
Yom, SS .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (08) :4459-4461