Microwave-Assisted Polymerizations: Recent Status and Future Perspectives

被引：153

作者：

Kempe, Kristian ^{[1
,2
]}

Becer, C. Remzi ^{[1
,3
]}

Schubert, Ulrich S. ^{[1
,2
,3
]}

机构：

[1] Univ Jena, Lab Organ & Macromol Chem IOMC, D-07743 Jena, Germany

[2] Univ Jena, Jena Ctr Soft Matter JCSM, D-07743 Jena, Germany

[3] Dutch Polymer Inst, NL-5612 AB Eindhoven, Netherlands

来源：

MACROMOLECULES | 2011年 / 44卷 / 15期

关键词：

RING-OPENING POLYMERIZATION; MEDIATED RADICAL POLYMERIZATION; OPTICALLY-ACTIVE POLYAMIDES; MOLECULAR-WEIGHT DEVELOPMENT; OF-THE-ART; IONIC LIQUIDS; EPSILON-CAPROLACTONE; TRIMETHYLENE CARBONATE; RAFT POLYMERIZATION; FLUORINATED; 2-PHENYL-2-OXAZOLINES;

D O I：

10.1021/ma2004794

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Microwave heating is frequently used in the synthesis of polymers owing to the precise temperature and pressure control when using monomodal microwave synthesizer. The ever since growing interest in this sort of heating source is expressed by a near-exponential increasing number of publications in this research field every year. This Perspective encompasses the progress of microwave-assisted polymerizations in the past four years with a special focus on controlled and living polymerizations. Furthermore, polymer syntheses under microwave irradiation in ionic liquids as well as the upscaling of microwave-assisted polymerizations are discussed with regard to an energy-saving green process and a potential expansion to industrial applications, respectively.

引用

页码：5825 / 5842

页数：18

共 121 条

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