Nickel-cobalt layered double hydroxide nanosheets anchored to the inner wall of wood carbon tracheids by nitrogen-doped atoms for high-performance supercapacitors

被引:56
作者
Li, Zuwei [1 ]
Wang, Xiaoman [1 ]
Wang, Ziheng [1 ]
Wang, Luchi [1 ]
Guo, Yuhang [1 ]
Zhou, Cui [1 ]
Li, Xianjun [1 ]
Du, Kun [1 ]
Luo, Yongfeng [1 ]
机构
[1] Cent South Univ Forestry & Technol, Coll Sci, Hunan Prov Key Lab Mat Surface & Interface Sci &, Changsha 410004, Peoples R China
基金
中国国家自然科学基金;
关键词
Supercapacitor; Nickel-cobalt layered double hydroxide; Wood-derived monolithic carbon; Nitrogen-doped carbon materials; HIGH-ENERGY; GRAPHENE; SHELL; ELECTRODE; ELECTROCATALYSTS; FOAM;
D O I
10.1016/j.jcis.2021.09.127
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper, a novel type of electrode material for high-performance hybrid supercapacitors is designed. The electrode mainly uses nitrogen-doped atoms to anchor the nickel-cobalt layered double hydroxide on the inner wall of wood-derived carbon tracheids from Chinese fir wood scraps. The specific capacity of the composite single electrode is 14.26 mAh cm(-2) at 10 mA cm(-2). The hybrid supercapacitor with a composite electrode cathode and nitrogen-doped wood-derived monolithic carbon materials as the anode has a high specific capacitance of 4.74F cm(-2) at 5 mA cm(-2), and the capacitance retention rate is 93.15% after 8000 charge-discharge cycles. The highest energy density and power density reach 1.48 mWh cm(-2) and 22.40 mW cm(-2), respectively. After doping with nitrogen, the combination with the nickel-cobalt layered double hydroxide is more uniform and stable, and the capacitance and cycling stability are significantly improved. (C) 2021 Elsevier Inc. All rights reserved.
引用
收藏
页码:70 / 78
页数:9
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