Light-triggered syneresis of a water insoluble peptide-hydrogel effectively removes small molecule waste contaminants

被引:35
作者
Das, Basab Kanti [1 ]
Pramanik, Bapan [1 ]
Chowdhuri, Sumit [1 ]
Scherman, Oren A. [2 ]
Das, Debapratim [1 ]
机构
[1] Indian Inst Technol Guwahati, Dept Chem, Gauhati 781039, Assam, India
[2] Univ Cambridge, Dept Chem, Melville Lab Polymer Synth, Cambridge CB2 1EW, England
关键词
SUPRAMOLECULAR HYDROGEL;
D O I
10.1039/c9cc09225k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A short peptide based hydrogel exhibits aqueous insolubility, thixotropy and efficient light induced syneresis. Upon irradiation with UV light, the hydrogel shrinks and expells similar to 50% of the solvent. Syneresis is caused by light-triggered trans-cis isomerisation of an azobenzene moiety in the peptide derivative. This expulsion of solvent can be effectively exploited in the removal of low molecular weight contaminants in water.
引用
收藏
页码:3393 / 3396
页数:4
相关论文
共 29 条
  • [1] A tripeptide-based self-shrinking hydrogel for waste-water treatment: removal of toxic organic dyes and lead (Pb2+) ions
    Basak, Shibaji
    Nandi, Nibedita
    Paul, Subir
    Hamley, Ian W.
    Banerjee, Arindam
    [J]. CHEMICAL COMMUNICATIONS, 2017, 53 (43) : 5910 - 5913
  • [2] Photo-mechanical azobenzene cocrystals and in situ X-ray diffraction monitoring of their optically-induced crystal-to-crystal isomerisation
    Bushuyev, Oleksandr S.
    Corkery, T. Christopher
    Barrett, Christopher J.
    Friscic, Tomislav
    [J]. CHEMICAL SCIENCE, 2014, 5 (08) : 3158 - 3164
  • [3] On the syneresis of an OPV functionalised dipeptide hydrogel
    Castilla, Ana M.
    Wallace, Matthew
    Mears, Laura L. E.
    Draper, Emily R.
    Doutch, James
    Rogers, Sarah
    Adams, Dave J.
    [J]. SOFT MATTER, 2016, 12 (37) : 7848 - 7854
  • [4] Tunable Pentapeptide Self-Assembled β-Sheet Hydrogels
    Clarke, David E.
    Parmenter, Christopher D. J.
    Scherman, Oren A.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (26) : 7709 - 7713
  • [5] Metastable hydrogels from aromatic dipeptides
    Conte, M. P.
    Singh, N.
    Sasselli, I. R.
    Escuder, B.
    Ulijn, R. V.
    [J]. CHEMICAL COMMUNICATIONS, 2016, 52 (96) : 13889 - 13892
  • [6] Peptide hydrogels
    Dasgupta, Antara
    Mondal, Julfikar Hassan
    Das, Debapratim
    [J]. RSC ADVANCES, 2013, 3 (24) : 9117 - 9149
  • [7] A low molecular weight hydrogel with unusual gel aging
    Draper, Emily R.
    McDonald, Tom O.
    Adams, Dave J.
    [J]. CHEMICAL COMMUNICATIONS, 2015, 51 (30) : 6595 - 6597
  • [8] Supramolecular Hydrogelators and Hydrogels: From Soft Matter to Molecular Biomaterials
    Du, Xuewen
    Zhou, Jie
    Shi, Junfeng
    Xu, Bing
    [J]. CHEMICAL REVIEWS, 2015, 115 (24) : 13165 - 13307
  • [9] A Self-Assembled Peptide-Appended Naphthalene Diimide: A Fluorescent Switch for Sensing Acid and Base Vapors
    Gayen, Kousik
    Basu, Kingshuk
    Nandi, Nibedita
    Das, Krishna Sundar
    Hermida-Merino, Daniel
    Hamley, Ian W.
    Banerjee, Arindam
    [J]. CHEMPLUSCHEM, 2019, 84 (11): : 1673 - 1680
  • [10] Small Bioactive Peptides for Biomaterials Design and Therapeutics
    Hamley, I. W.
    [J]. CHEMICAL REVIEWS, 2017, 117 (24) : 14015 - 14041