A tetraphenylimidazole-based fluorescent probe for the detection of hydrogen sulfide and its application in living cells

被引：31

作者：

Gu, Biao ^{[1
]}

Mi, Naxiu ^{[1
]}

Zhang, Youyu ^{[1
]}

Yin, Pen ^{[1
]}

Li, Haitao ^{[1
]}

Yao, Shouzhuo ^{[1
]}

机构：

[1] Hunan Normal Univ, Coll Chem & Chem Engn, Key Lab Chem Biol & Tradit Chinese Med Res, Minist Educ, Changsha 410081, Hunan, Peoples R China

来源：

ANALYTICA CHIMICA ACTA | 2015年 / 879卷

基金：

国家教育部博士点专项基金资助; 中国国家自然科学基金;

关键词：

Probe; Hydrogen sulfide; ESIPT; Cellular imaging; SELECTIVE DETECTION; H2S; ESIPT; NEUROMODULATOR; RECOGNITION; CHANNELS; BLOOD;

D O I：

10.1016/j.aca.2015.03.017

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A novel probe based on the fluorescence off-on strategy was prepared to optically detect hydrogen sulfide (H2S) via an excited state intramolecular proton transfer (ESIPT) mechanism. The probe shows high sensitivity and excellent selectivity to H2S. It also displays a large Stokes shift (similar to 140 nm) and a remarkable quantum yield enhancement (Phi = 0.412) after interaction with H2S. Moreover, the cellular imaging experiment demonstrated that it has potential utility for H2S sensing in biological sciences. (C) 2015 Elsevier B.V. All rights reserved.

引用

收藏

页码：85 / 90

页数：6

相关论文

共 45 条

[1]

Abe K, 1996, J NEUROSCI, V16, P1066

[2] A sensitivity tuneable tetraphenylethene-based fluorescent probe for directly indicating the concentration of hydrogen sulfide [J].

Cai, Yunbo ;

Li, Lingzhi ;

Wang, Zongtan ;

Sun, Jing Zhi ;

Qin, Anjun ;

Tang, Ben Zhong .

CHEMICAL COMMUNICATIONS, 2014, 50 (64) :8892-8895

[3] Rhodamine-propargylic esters for detection of mitochondrial hydrogen sulfide in living cells [J].

Chen, Xi ;

Wu, Shuqi ;

Han, Jiahuai ;

Han, Shoufa .

BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2013, 23 (19) :5295-5299

[4] Sulfide-selective chemosignaling by a Cu2+ complex of dipicolylamine appended fluorescein [J].

Choi, Myung Gil ;

Cha, Sunyoung ;

Lee, Haekyung ;

Jeon, Hye Lim ;

Chang, Suk-Kyu .

CHEMICAL COMMUNICATIONS, 2009, (47) :7390-7392

[5] RETRACTED: Brain hydrogen sulfide is severely decreased in Alzheimer's disease (Retracted Article) [J].

Eto, K ;

Asada, T ;

Arima, K ;

Makifuchi, T ;

Kimura, H .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 2002, 293 (05) :1485-1488

[6] The third gas:: H2S regulates perfusion pressure in both the isolated and perfused normal rat liver and in cirrhosis [J].

Fiorucci, S ;

Antonelli, E ;

Mencarelli, A ;

Orlandi, S ;

Renga, B ;

Rizzo, G ;

Distrutti, E ;

Shah, V ;

Morelli, A .

HEPATOLOGY, 2005, 42 (03) :539-548

[7] Development of a boron-dipyrromethene-Cu2+ ensemble based colorimetric probe toward hydrogen sulfide in aqueous media [J].

Gu, Xianfeng ;

Liu, Chunhua ;

Zhu, Yi-Chun ;

Zhu, Yi-Zhun .

TETRAHEDRON LETTERS, 2011, 52 (39) :5000-5003

[8] Plasmon Enhancement and Surface Wave Quenching for Phase Ratiometry in Coextraction-Based Fluorosensors [J].

Hakonen, Aron .

ANALYTICAL CHEMISTRY, 2009, 81 (11) :4555-4559

[9] Recognition of copper and hydrogen sulfide in vitro using a fluorescein derivative indicator [J].

Hou, Fengping ;

Cheng, Ju ;

Xi, Pinxian ;

Chen, Fengjuan ;

Huang, Liang ;

Xie, Gouqiang ;

Shi, Yanjun ;

Liu, Hongyan ;

Bai, Decheng ;

Zeng, Zhengzhi .

DALTON TRANSACTIONS, 2012, 41 (19) :5799-5804

[10] A Retrievable and Highly Selective Fluorescent Probe for Monitoring Sulfide and Imaging in Living Cells [J].

Hou, Fengping ;

Huang, Liang ;

Xi, Pinxian ;

Cheng, Ju ;

Zhao, Xuefei ;

Xie, Guoqiang ;

Shi, Yanjun ;

Cheng, Fengjuan ;

Yao, Xiaojun ;

Bai, Decheng ;

Zeng, Zhengzhi .

INORGANIC CHEMISTRY, 2012, 51 (04) :2454-2460

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