A versatile bio-based material for efficiently removing toxic dyes, heavy metal ions and emulsified oil droplets from water simultaneously

被引:56
作者
Li, Daikun [1 ]
Li, Qing [1 ]
Mao, Daoyong [1 ]
Bai, Ningning [1 ]
Dong, Hongzhou [1 ]
机构
[1] Southwest Univ, Sch Chem & Chem Engn, Tiansheng Rd 2, Chongqing 400715, Peoples R China
基金
中国国家自然科学基金;
关键词
Bio-based material; Toxic dyes; Heavy metal ions; Oil/water separation; OIL/WATER SEPARATION; AQUEOUS-SOLUTIONS; ADSORPTION-KINETICS; BETA-CYCLODEXTRIN; HYDROGEL BEADS; CATIONIC DYES; ANIONIC DYES; COATED MESH; ADSORBENT; MICROSPHERES;
D O I
10.1016/j.biortech.2017.09.016
中图分类号
S2 [农业工程];
学科分类号
0828 ;
摘要
Developing versatile materials for effective water purification is significant for environment and water source protection. Herein, a versatile bio-based material (CH-PAA-T) was reported by simple thermal cross-linking chitosan and polyacrylic acid which exhibits excellent performances for removing insoluble oil, soluble toxic dyes and heavy metal ions from water, simultaneously. The adsorption capacities are 990.1 mg g(-1) for methylene blue (MB) and 135.9 mg g(-1) for Cu2+, which are higher than most of present advanced absorbents. The adsorption towards organic dyes possesses high selectivity which makes CH-PAA-T be able to efficiently separate dye mixtures. The stable superoleophobicity under water endows CH-PAA-T good performance to separate toluene- in-water emulsion stabilized by Tween 80. Moreover, CH-PAA-T can be recycled for 10 times with negligible reduction of efficiency. Such versatile bio-based material is a potential candidate for water purification.
引用
收藏
页码:649 / 655
页数:7
相关论文
共 44 条
[1]   A novel polyvinyltetrazole-grafted resin with high capacity for adsorption of Pb(II), Cu(II) and Cr(III) ions from aqueous solutions [J].
Chen, Youning ;
He, Maofang ;
Wang, Chaozhan ;
Wei, Yinmao .
JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (27) :10444-10453
[2]   One-Step Fabrication of Graphene Oxide Enhanced Magnetic Composite Gel for Highly Efficient Dye Adsorption and Catalysis [J].
Cheng, Zehong ;
Liao, Jie ;
He, Benzhao ;
Zhang, Fan ;
Zhang, Faai ;
Huang, Xiaohua ;
Zhou, Li .
ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2015, 3 (07) :1677-1685
[3]   Oil/Water Separation with Selective Superantiwetting/Superwetting Surface Materials [J].
Chu, Zonglin ;
Feng, Yujun ;
Seeger, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (08) :2328-2338
[4]   Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions [J].
Dai, Jie ;
Yan, Han ;
Yang, Hu ;
Cheng, Rongshi .
CHEMICAL ENGINEERING JOURNAL, 2010, 165 (01) :240-249
[5]   Kinetic, equilibrium and thermodynamic phenomenological modeling of reactive dye adsorption onto polymeric adsorbent [J].
Dias Monte Blanco, Silvia Priscila ;
Scheufele, Fabiano Bisinella ;
Modenes, Aparecido Nivaldo ;
Espinoza-Quinones, Fernando R. ;
Marin, Pricila ;
Kroumov, Alexander Dimitrov ;
Borba, Carlos Eduardo .
CHEMICAL ENGINEERING JOURNAL, 2017, 307 :466-475
[6]   Multilayer Dye Adsorption in Activated Carbons-Facile Approach to Exploit Vacant Sites and Interlayer Charge Interaction [J].
Hadi, Pejman ;
Guo, Jiaxin ;
Barford, John ;
McKay, Gordon .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2016, 50 (10) :5041-5049
[7]   Species differences in the metabolism of olefins: implications for risk assessment [J].
Henderson, RF .
CHEMICO-BIOLOGICAL INTERACTIONS, 2001, 135 :53-64
[8]   Mechanisms of lead adsorption on chitosan/PVA hydrogel beads [J].
Jin, L ;
Bai, RB .
LANGMUIR, 2002, 18 (25) :9765-9770
[9]   Adsorption of anionic dyes on chitosan grafted poly(alkyl methacrylate)s [J].
Konaganti, Vinod Kumar ;
Kota, Ramanjaneyulu ;
Patil, Satish ;
Madras, Giridhar .
CHEMICAL ENGINEERING JOURNAL, 2010, 158 (03) :393-401
[10]   Porous boron nitride nanosheets for effective water cleaning [J].
Lei, Weiwei ;
Portehault, David ;
Liu, Dan ;
Qin, Si ;
Chen, Ying .
NATURE COMMUNICATIONS, 2013, 4