Iron and vanadium containing molybdophosphoric acid catalyst for selective oxidation of alcohols with molecular oxygen

被引：30

作者：

Nagaraju, P. ^{[1
]}

Pasha, Nayeem ^{[1
]}

Prasad, P. S. Sai ^{[1
]}

Lingaiah, N. ^{[1
]}

机构：

[1] Indian Inst Chem Technol, Catalysis Lab, I&PC Div, Hyderabad 500007, Andhra Pradesh, India

来源：

GREEN CHEMISTRY | 2007年 / 9卷 / 10期

关键词：

D O I：

10.1039/b618546k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The Keggin type 12- molybdophosphoric acid is modified by incorporation of vanadium and iron and studied for oxidation of various alcohols using molecular oxygen as oxidant. The molybdophoshoric acid catalyst containing both vanadium and iron is highly active compared with the catalysts containing either vanadium or iron in the Keggin structure. The iron exchanged vanadium incorporated molydophosphoric acid catalyst is active for the oxidation of various primary and secondary alcohols under mild conditions and reusable without any appreciable loss in activity.

引用

页码：1126 / 1129

页数：4

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