Fabrication and Characterization of Prussian Blue-Derived Iron Carbide-Iron Oxide Hybrid on Reduced Graphene Oxide Nanosheets

被引:2
作者
Azhar, Alowasheeir [1 ]
Earnshaw, Jacob [2 ]
Zakaria, Mohamed Barakat [1 ,2 ]
Cheng, Ping [2 ]
Kaneti, Yusuf Valentino [1 ]
Hossain, Md Shahriar A. [2 ,3 ]
Alshehri, Saad M. [4 ]
Ahamad, Tansir [4 ]
Yamauchi, Yusuke [2 ,5 ,6 ]
Na, Jongbeom [1 ,2 ]
机构
[1] Natl Inst Mat Sci NIMS, Int Ctr Mat Nanoarchitecton MANA, 1-1 Namiki, Tsukuba, Ibaraki 3050044, Japan
[2] Univ Queensland, Australian Inst Bioengn & Nanotechnol AIBN, Brisbane, Qld 4072, Australia
[3] Univ Queensland, Fac Engn Architecture & Informat Technol EAIT, Sch Mech & Min Engn, Brisbane, Qld, Australia
[4] King Saud Univ, Coll Sci, Dept Chem, Riyadh, Saudi Arabia
[5] Univ Queensland, Sch Chem Engn, Brisbane, Qld, Australia
[6] Kyung Hee Univ, Dept Plant & Environm New Resources, Yongin, South Korea
关键词
metal-organic frameworks; porous coordination polymers; metal oxides; metal carbides; graphene oxide; REDUCTION; CARBON; NANOCOMPOSITES; NANOPARTICLES; NANOCRYSTALS; NANOCUBES; GROWTH;
D O I
10.14356/kona.2021015
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
This work demonstrates the fabrication of a nanoporous iron carbide-iron oxide/reduced graphene oxide (IC-IO/rGO) hybrid via a controlled one-step thermal treatment of Prussian blue (PB)/GO hybrid at 450 degrees C under N-2 flow. The PB/GO hybrid is initially prepared through the in-situ deposition of PB nanoparticles on the GO sheets through electrostatic interactions. The morphological analysis of the hybrid reveals the uniform coverage of the rGO sheets by IC-IO nanoparticles and the even distribution of carbon (C), oxygen (O), and iron (Fe) on the rGO nanosheets. As a result of the hybrid composition and controlled morphology, the surface area of the obtained IC-IO/rGO hybrid (similar to 40 m(2)/g) is significantly enhanced compared to those of the calcined GO sheets and PB nanoparticles (without GO).
引用
收藏
页码:260 / 268
页数:9
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