Neutral palladium(II) complexes with P,N Schiff-base ligands: Synthesis, characterization and application as Suzuki-Miyaura coupling catalysts

被引：49

作者：

Mahamo, Tebello ^{[1
,3
]}

Mogorosi, Mokgolela M. ^{[1
]}

Moss, John R. ^{[1
]}

Mapolie, Selwyn F. ^{[2
]}

Slootweg, J. Chris ^{[3
]}

Lammertsma, Koop ^{[3
]}

Smith, Gregory S. ^{[1
]}

机构：

[1] Univ Cape Town, Dept Chem, ZA-7701 Rondebosch, South Africa

[2] Univ Stellenbosch, Dept Chem & Polymer Sci, Matieland, South Africa

[3] Vrije Univ Amsterdam, Fac Sci, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2012年 / 703卷

基金：

新加坡国家研究基金会;

关键词：

Arylboronic acids; Aryl halides; Suzuki-Miyaura coupling; Iminophosphines; Palladium(II) complexes; METAL-COMPLEXES; HECK REACTION; IMINOPHOSPHINE LIGANDS; PLATINUM(II) COMPLEXES; DONOR SETS; PHOSPHINE; REACTIVITY; TRANSMETALATION; OLIGOMERIZATION; HYDROGENATION;

D O I：

10.1016/j.jorganchem.2011.12.021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium(II) complexes of the general formulae [PdCl2((PN)-N-boolean AND)] and [Pd(Me)Cl((PN)-N-boolean AND)] were obtained from bidentate ligands bearing phosphine and imine donor groups. The complexes were shown to be highly active catalysts for the Suzuki-Miyaura cross-coupling reaction. The complexes are tolerant of a wide variety of reaction conditions such as solvent, choice of base as well as substituents on both arylboronic acids and aryl halides. (C) 2012 Elsevier B.V. All rights reserved.

引用

页码：34 / 42

页数：9

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