Thermodynamic properties of caesium-magnesium monophosphate

被引：13
|
作者：
Asabina, E. A. [1 ]
Zaripov, A. R. [2 ]
Pet'kov, V. I. [1 ]
Markin, A. V. [1 ]
Kir'yanov, K. V. [1 ]
Smirnova, N. N. [1 ]
Rovny, S. I. [2 ]
机构：
[1] Nizhnii Novgorod State Univ, Nizhnii Novgorod 603950, Russia
[2] Mayak PA, Ozersk 456780, Chelyabinskaya, Russia
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2008年 / 40卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
phosphate; stuffed tridymite structure; caesium; heat capacity; thermodynamic functions; solution reaction calorimetry;
D O I：
10.1016/j.jct.2007.11.001
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The heat capacity measurements of the crystalline phosphate CsMgPO4 of a tridymite structure were performed between T = (7 and 650) K. The thermodynamic functions C-p,C-m degrees/R, Delta H-T(0)m degrees/RT, Delta S-T(0)m degrees/R, and Phi(m)degrees/R were calculated and the fractal dimension D-fr evaluated. From the solution reaction calorimetry, the standard enthalpy of CSMgPO4 formation at T = 298.15 K was found. Thermochemical parameters of formation Delta(f)G(m)degrees and lgK(f,m)degrees were determined by combining the data obtained by these techniques. (C) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码：653 / 660
页数：8
相关论文
共 50 条
  • [31] Thermodynamic properties of tetrabutylammonium iodide and tetrabutylammonium tetraphenylborate
    Smirnova, N. N.
    Tsvetkova, L. Ya.
    Bykova, T. A.
    Ruchenin, V. A.
    Marcus, Yizhak
    THERMOCHIMICA ACTA, 2009, 483 (1-2) : 15 - 20
  • [32] Thermodynamic properties of rubidium niobium tungsten oxide
    Aleksandr Knyazev
    Mirosław Mączka
    Nataliya Kuznetsova
    Jerzy Hanuza
    Aleksey Markin
    Journal of Thermal Analysis and Calorimetry, 2009, 98 : 843 - 848
  • [33] Thermodynamic properties of vitamin B9
    Knyazev, A. V.
    Emel'yanenko, V. N.
    Shipilova, A. S.
    Lelet, M. I.
    Gusarova, E. V.
    Knyazeva, S. S.
    Verevkin, S. P.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2016, 100 : 185 - 190
  • [34] Thermodynamic and spectroscopic properties of KNbTeO6
    Knyazev, A. V.
    Paraguassu, W.
    Blokhina, A. G.
    Lelet, M. I.
    Knyazeva, S. S.
    Correa Junior, G. B.
    JOURNAL OF CHEMICAL THERMODYNAMICS, 2017, 107 : 26 - 36
  • [35] Thermodynamic properties of rubidium niobium tungsten oxide
    Knyazev, Aleksandr
    Maczka, Miroslaw
    Kuznetsova, Nataliya
    Hanuza, Jerzy
    Markin, Aleksey
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (03) : 843 - 848
  • [36] Thermodynamic properties of tetraphenylantimony 1-adamantanecarboxylate
    D. V. Lyakaev
    A. V. Markin
    N. N. Smirnova
    V. V. Sharutin
    O. K. Sharutina
    Journal of Thermal Analysis and Calorimetry, 2018, 133 : 1143 - 1148
  • [37] Thermodynamic properties of pentalead tris(vanadate) chloride
    Knyazev, A. V.
    Bulanov, E. N.
    Smirnova, N. N.
    Kuznetsova, N. Yu.
    Letyanina, I. A.
    Pryamova, E. D.
    THERMOCHIMICA ACTA, 2011, 515 (1-2) : 79 - 83
  • [38] Thermodynamic properties of vitamin B2
    Knyazev, A. V.
    Letyanina, I. A.
    Plesovskikh, A. S.
    Smirnova, N. N.
    Knyazeva, S. S.
    THERMOCHIMICA ACTA, 2014, 575 : 12 - 16
  • [39] Internally consistent thermodynamic data for magnesium sulfate hydrates
    Grevel, Klaus-Dieter
    Majzlan, Juraj
    GEOCHIMICA ET COSMOCHIMICA ACTA, 2009, 73 (22) : 6805 - 6815
  • [40] Thermodynamic Properties of Formylferrocene
    M. S. Kozlova
    N. V. Karyakin
    M. S. Sheiman
    V. N. Larina
    G. P. Kamelova
    Russian Journal of General Chemistry, 2004, 74 : 341 - 345
12345