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Dealloying of MgZn2 Intermetallic in Slightly Alkaline Chloride Electrolyte and Its Significance in Corrosion Resistance
被引:45
作者:
Han, J.
[1
]
Ogle, K.
[1
]
机构:
[1] PSL Res Univ, CNRS, IRCP, Chim ParisTech, F-75005 Paris, France
关键词:
ZN-AL-MG;
ANODIC-DISSOLUTION;
COATED STEEL;
CUT EDGE;
ELECTROCHEMICAL-BEHAVIOR;
SODIUM-CHLORIDE;
MAGNESIUM;
ZINC;
MICROSTRUCTURE;
MECHANISM;
D O I:
10.1149/2.0341714jes
中图分类号:
O646 [电化学、电解、磁化学];
学科分类号:
081704 ;
摘要:
The role of dealloying in the corrosion resistance of MgZn2 has been investigated for the first time. The elemental dissolution kinetics of a synthetic, nominally pure MgZn2 intermetallic compound was investigated and compared with pure Mg and Zn in 30 mM NaCl with pH = 10.1. Atomic emission spectroelectrochemistry was used to monitor Zn and Mg dissolution as a function of time at open circuit, during linear scan polarization, and at various applied potentials. Zn and Mg displayed a mutual inhibitive effect at open circuit which was explained by the formation of Mg depleted Zn / Zn oxide film. Polarization experiments revealed a Type II dealloying mechanism in which Zn and Mg dissolve simultaneously and congruently above the critical potential, E-c, while preferential Mg dissolution dominates below Ec. Preferential Mg dissolution leads to the formation of a Mg depleted metallic Zn layer which suppresses further Mg dissolution. In oxygen saturated electrolyte, O-2 reduction was the major cathodic reaction on Zn but was completely inhibited on Mg. The intense cathodic reduction of O-2 on Zn led to a cathodic dissolution of Zn, probably due to the increased interfacial pH. (c) The Author(s) 2017. Published by ECS. All rights reserved.
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页码:C952 / C961
页数:10
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