New environmentally friendly catalysts containing Pd-interstitial carbon made from Pd-glucose precursors for ultraselective hydrogenations in the liquid phase

被引：45

作者：

Chan, Chun Wong Aaron ^{[1
]}

Xie, Yaling ^{[1
]}

Cailuo, Nick ^{[1
]}

Yu, Kai Man Kerry ^{[1
]}

Cookson, James ^{[2
]}

Bishop, Peter ^{[2
]}

Tsang, Shik Chi ^{[1
]}

机构：

[1] Univ Oxford, Wolfson Catalysis Ctr, Dept Chem, Oxford OX1 3QR, England

[2] Johnson Matthey Technol Ctr, Reading RG4 7NH, Berks, England

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 28期

关键词：

D O I：

10.1039/c1cc12681d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a novel preparation of a Pd nanocatalyst modified with subsurface C via blending a glucose precursor at the molecular level: the catalyst is demonstrated for the first time to be stereoselective in the hydrogenation of alkynes to cis-alkenes in the liquid phase.

引用

页码：7971 / 7973

页数：3

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