High-Resolution Infrared Spectroscopy of the v1 + v4 Band of 14NF3: Reductions of the Rovibrational Hamiltonian

被引：10
|
作者：
Najib, Hamid [1 ]
Hmimou, Siham [1 ]
Msahal, Hicham [1 ]
机构：
[1] Univ Ibn Tofail, Dept Phys, Fac Sci, Kenitra 14000, Morocco
来源：
E-JOURNAL OF CHEMISTRY | 2012年 / 9卷 / 01期
关键词：
Nitrogen trifluoride NF3; FTIR spectroscopy; Rovibration; Combination band; Reductions; Equivalences; SYMMETRIC TOP MOLECULES; NITROGEN TRIFLUORIDE; VIBRATIONAL-STATE; MILLIMETER-WAVE; ROTATIONAL SPECTRUM; CENTIMETER-WAVE; (NF3)-N-14; RESONANCE; FTIR; NU(N)(A(1));
D O I：
10.1155/2012/218684
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The high-resolution Fourier transform infrared spectrum of nitrogen trifluoride NF3 has been studied in the v(1) + v(4) perpendicular band region around 1523 cm(-1). All experimental data have been refined applying various reduction forms of the effective rovibrational Hamiltonian developed for an isolated degenerate state of a symmetric top molecule. The v(1) = v(4) = 1 excited state of the (NF3)-N-14 oblate molecule was treated with models taking into account l- and k-type intravibrational resonances. Parameters up to sixth order have been accurately determined and the unitary equivalence of the derived parameter sets in different reductions was demonstrated.
引用
收藏
页码：253 / 259
页数：7
相关论文
共 30 条
  • [11] The high-resolution infrared spectrum of the v3 + v5 combination band of jet-cooled propyne
    Doney, K. D.
    Zhao, D.
    Bouwman, J.
    Linnartz, H.
    CHEMICAL PHYSICS LETTERS, 2017, 684 : 351 - 356
  • [12] Rovibrational constants of the ground and v12=1 states of C2D4 by high-resolution synchrotron FTIR spectroscopy
    Tan, T. L.
    Gabona, M. G.
    Appadoo, Dominique R. T.
    Godfrey, Peter D.
    McNaughton, Don
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2014, 303 : 42 - 45
  • [13] An Analysis of the High-Resolution Spectrum of the Weak v 1 +v 2 +v 3 Absorption Band of the SO2 Molecule
    Belova, A. S.
    Bolotova, I. B.
    Gromova, O. V.
    Bekhtereva, E. S.
    Ulenikov, O. N.
    RUSSIAN PHYSICS JOURNAL, 2015, 57 (11) : 1518 - 1524
  • [14] High-resolution infrared spectroscopy of the interacting v9, v5 + v6 and 3v6 levels of CH279BrF
    Visinoni, R.
    Baldacci, A.
    Larsen, R. Wugt
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2011, 269 (02) : 226 - 230
  • [15] Improved rovibrational constants for the ν6 + ν10 band of ethylene (12C2H4) by high-resolution Fourier transform infrared spectroscopy
    Lebron, G. B.
    Tan, T. L.
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2013, 283 : 29 - 31
  • [16] High-resolution FTIR spectroscopy of the v7 and v8 bands of 1-phosphapropyne
    Bane, Michael K.
    Jones, Cameron
    Choong, Sam L.
    Thompson, Christopher D.
    Godfrey, Peter D.
    Appadoo, Dominique R. T.
    McNaughton, Don
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2012, 275 : 9 - 14
  • [17] Rovibrational analysis of the ethylene isotopologue 13C2D4 by high-resolution Fourier transform infrared spectroscopy
    Tan, T. L.
    Gabona, M. G.
    Godfrey, Peter D.
    McNaughton, Don
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2015, 307 : 40 - 43
  • [18] High-resolution FTIR spectroscopy of CHD279Br: ro-vibrational analysis of the v4 fundamental and determination of the ground state constants
    Stoppa, P.
    Zampatto, A.
    Baldacci, A.
    Giorgianni, S.
    Larsen, R. Wugt
    MOLECULAR PHYSICS, 2020, 118 (01)
  • [19] High-resolution Fourier transform infrared spectrum of the v11 band of ethylene (12C2H4)
    Lebron, G. B.
    Tan, T. L.
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2013, 288 : 11 - 13
  • [20] High-resolution Fourier transform infrared spectrum of the v6 band of formamide-d1 (DCONH2)
    Wu, Q. Y.
    Tan, T. L.
    Ng, L. L.
    Appadoo, Dominique R. T.
    JOURNAL OF MOLECULAR SPECTROSCOPY, 2019, 363
123