Traceless directing group mediated branched selective alkenylation of unbiased arenes

被引：42
作者：
Agasti, Soumitra [1 ]
Dey, Aniruddha [1 ]
Maiti, Debabrata [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 82期
关键词：
C-H OLEFINATION; CROSS-COUPLING REACTIONS; OXIDATIVE HECK REACTION; CATALYZED DIRECT ARYLATION; BOND ACTIVATION; POLYSUBSTITUTED OLEFINS; ORGANOMETALLIC CHEMISTRY; PALLADIUM CATALYST; METAL-COMPLEXES; ARYL HALIDES;
D O I：
10.1039/c6cc07032a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Owing to the synthetic importance of branched olefinated products, we report palladium catalyzed formation of branched olefins facilitated by a C-H activation based protocol. This involves selective insertion of olefins and subsequent decarboxylation using a completely unbiased benzene ring as the starting precursor. The significance of the protocol has been further highlighted by exhibition of functionality tolerance along with a late-stage modification of the branched olefinated products leading to the formation of other functionalized molecules.
引用
收藏
页码：12191 / 12194
页数：4
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