A general and convenient route to oxazolyl ligands

被引：22
作者：
Aspinall, Helen C. [1 ]
Beckingham, Oliver [1 ]
Farrar, Michael D. [1 ]
Greeves, Nicholas [1 ]
Thomas, Christopher D. [1 ]
机构：
[1] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
TETRAHEDRON LETTERS | 2011年 / 52卷 / 40期
基金：
英国工程与自然科学研究理事会;
关键词：
Oxazolyl ligand; Oxazoline; Chiral ligand; Oxazolyl phenol; SELECTIVE REACTIONS; COMPLEXES; ALDEHYDES; PHENOLS; ZN(HPB)(2); CONVERSION;
D O I：
10.1016/j.tetlet.2011.07.070
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A diverse range of chiral and achiral oxazolyl ligands, which have many applications including catalysis and luminescent devices, are synthesized simply in three steps from readily available and inexpensive phenol and amino alcohol starting materials. The method can be applied to ligands with electron-donating/-withdrawing and sterically demanding/undemanding substituents, and can conveniently be scaled up to >25 g of product. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5120 / 5123
页数：4
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