One-Pot Method to Synthesize Silver Nanoparticle-Modified Bamboo-Based Carbon Aerogels for Formaldehyde Removal

被引:5
|
作者
Jing, Wenxiang [1 ,2 ]
Yang, Chai [2 ]
Luo, Shuang [3 ]
Lin, Xiaoyan [1 ]
Tang, Min [2 ]
Zheng, Renhong [2 ]
Lian, Dongming [2 ]
Luo, Xuegang [1 ]
机构
[1] Southwest Univ Sci & Technol, Engn Res Ctr Biomass Mat, Minist Educ, Mianyang 621002, Sichuan, Peoples R China
[2] Yibin Ind Acad Forestry & Bamboo, Yibin 644005, Peoples R China
[3] Yibin Univ, Sichuan Tea Coll, Yibin 644000, Peoples R China
关键词
silver nanoparticle; bamboo-based carbon aerogel; adsorption; formaldehyde; AG/CEO2; NANOSPHERES; ACTIVATED CARBON; CO OXIDATION; CATALYSTS; ADSORPTION; KINETICS;
D O I
10.3390/polym14050860
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The present study demonstrated a freeze-drying-carbonization method to synthesize silver nanoparticle-modified bamboo-based carbon aerogels to remove formaldehyde. The bamboo-based carbon aerogel (BCA) has the advantages of controllable pore size and rich oxygen-containing groups, which can provide a good foundation for surface modification. BCA can greatly enhance the purification of formaldehyde by loading silver nanoparticles. The maximum adsorption capacity of 5% Ag/BCA for formaldehyde reached 42 mg/g under 25 ppm formaldehyde concentration, which is 5.25 times more than that of BCA. The relevant data were fitted by the Langmuir model and the pseudo 2nd-order model and good results were obtained, indicating that chemical absorption occurred between the carbonyl of formaldehyde and the hydroxyl of BCA. Therefore, silver nanoparticle-modified bamboo-based carbon aerogels play a positive role in the selective removal of formaldehyde. Silver nanoparticles promoted the activation of oxygen and strengthened the effect of BCA on HCHO adsorption.
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页数:13
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