Natural iron oxalates and their analogous synthetic counterparts: A review

被引：23
作者：
Baran, Enrique J. [1 ]
机构：
[1] Univ Nacl La Plata, Fac Ciencias Exactas, Ctr Quim Inorgan, CEQUINOR CONICET, C Correo 962, RA-1900 La Plata, Buenos Aires, Argentina
来源：
CHEMIE DER ERDE-GEOCHEMISTRY | 2016年 / 76卷 / 03期
关键词：
Fe-oxalate minerals; Synthetic analogous complexes; Synthesis; Structural characteristics; Thermal behavior; Spectroscopic and magnetic properties; POLARIZED VISIBLE SPECTRA; THERMAL-DECOMPOSITION; CRYSTAL-STRUCTURE; CALCIUM-OXALATE; VIBRATIONAL-SPECTRA; MAGNETIC-SUSCEPTIBILITY; NEUTRON-DIFFRACTION; MOLECULAR-STRUCTURE; RAMAN-SPECTROSCOPY; METAL-COMPLEXES;
D O I：
10.1016/j.chemer.2016.06.005
中图分类号：
P3 [地球物理学]; P59 [地球化学];
学科分类号：
0708 ; 070902 ;
摘要：
Four iron-containing natural oxalates, usually classified as organic minerals, are known (humboldtine, minguzzite, stepanovite and zhemchuzhnikovite). Their occurrences and general properties are presented and briefly discussed. The subsequent part of the review is devoted to the discussion of synthetic oxalato-complexes, analogous to these natural species, including usual synthetic procedures and a thorough analysis of their crystallographic and structural peculiarities. The thermal, spectroscopic and magnetic properties of these complexes are also analyzed in detail and comparisons with other closely related complexes are also included in the discussions. (C) 2016 Elsevier GmbH. All rights reserved.
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收藏
页码：449 / 460
页数：12
相关论文
共 124 条
[1]   SYNTHESIS AND MOSSBAUER STUDY OF IRON OXALATE COORDINATION POLYMERS OF THE TYPE FE(C2O4)(L)X(H2O)2-X [J].
ABRAS, A ;
DEOLIVEIRA, EF .
HYPERFINE INTERACTIONS, 1991, 66 (1-4) :271-278
[2]   Weathering of rocks and neogenesis of minerals associated with lichen activity [J].
Adamo, P ;
Violante, P .
APPLIED CLAY SCIENCE, 2000, 16 (5-6) :229-256
[3]  
[Anonymous], 1955, AM MINERAL
[4]  
[Anonymous], 1997, AN ACAD BRAS CIENCIA
[5]  
[Anonymous], EXPT INORGANIC CHEM
[6]  
[Anonymous], ZN J ARGENT CHEM SOC
[7]  
[Anonymous], INORGANIC SYNTHESIS
[8]  
[Anonymous], 2015, IJIRSET
[9]  
[Anonymous], REACTIONS SOLID STAT
[10]  
[Anonymous], 1957, PER MINER
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