Realizing the Potential High Benefits of Circular Economy in the Chemical Industry: Ethylene Monomer Recovery via Polyethylene Pyrolysis

被引:75
|
作者
Somoza-Tornos, Ana [2 ]
Gonzalez-Garay, Andres [3 ]
Pozo, Carlos [3 ]
Graells, Moises [2 ]
Espuna, Antonio [2 ]
Guillen-Gosalbez, Gonzalo [1 ]
机构
[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland
[2] Univ Politecn Cataluna, Dept Chem Engn, Barcelona 08019, Spain
[3] Imperial Coll, Ctr Proc Syst Engn, Dept Chem Engn, South Kensington Campus, London SW7 2AZ, England
来源
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2020年 / 8卷 / 09期
关键词
Circular economy; Sustainability; Polyethylene; Life cycle assessment (LCA); Economic assessment; HIGH-DENSITY POLYETHYLENE; WASTE; GASIFICATION; INCINERATION; TEMPERATURE; POLYMERS; OLEFINS; YIELD;
D O I
10.1021/acssuschemeng.9b04835
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The concept of circular economy has gained wide interest in industry as a powerful strategy to reduce impacts while remaining economically competitive. Here, we explore the benefits of this approach in the chemical industry, quantifying explicitly the economic and environmental benefits of ethylene recovery from polyethylene plastics using process modeling coupled with Life Cycle Assessment (LCA). Our results show that the recovered ethylene represents a win-win alternative, offering a highly competitive cost of 0.386 (sic)/kg vs 0.835 (sic)1 kg with the standard naphtha-based route. Furthermore, substantial reductions of as much as 87%, 89%, and 164% could also be attained (compared to the naphtha-based ethylene) in impacts on human health, ecosystem quality, and resources scarcity, respectively. Overall, this work aims to promote the adoption of circular economy strategies in the chemical sector, while highlighting the role of process modeling, LCA, and systems thinking in quantifying the associated benefits to build strong cases for policymaking.
引用
收藏
页码:3561 / 3572
页数:23
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