Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions

被引：13
|
作者：
Srikanth, A
Nagendrappa, G
Chandrasekaran, S
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
[2] Bangalore Univ, Dept Chem, Bangalore 560001, Karnataka, India
来源：
TETRAHEDRON | 2003年 / 59卷 / 39期
关键词：
epoxidation; ruthenium; vinylsilanes; molecular oxygen;
D O I：
10.1016/S0040-4020(03)01210-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of -SiMe3 group on the rate of epoxidation process. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7761 / 7765
页数：5
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