Catalytic epoxidation of cyclic vinylsilanes by ruthenium(II) complexes under aerobic conditions

被引：13
|
作者：
Srikanth, A
Nagendrappa, G
Chandrasekaran, S
机构：
[1] Indian Inst Sci, Dept Organ Chem, Bangalore 560012, Karnataka, India
[2] Bangalore Univ, Dept Chem, Bangalore 560001, Karnataka, India
来源：
TETRAHEDRON | 2003年 / 59卷 / 39期
关键词：
epoxidation; ruthenium; vinylsilanes; molecular oxygen;
D O I：
10.1016/S0040-4020(03)01210-9
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new methodology has been developed for the catalytic epoxidation of cyclic vinylsilanes using a ruthenium(II) bisoxazoline complex 2 with molecular oxygen. An attempt has been made to understand the role of -SiMe3 group on the rate of epoxidation process. (C) 2003 Elsevier Ltd. All rights reserved.
引用
收藏
页码：7761 / 7765
页数：5
相关论文
共 50 条
  • [1] Competitive catalytic epoxidation and oxidative cleavage of stilbene by ruthenium complexes
    Morvillo, A
    Bressan, M
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1997, 125 (2-3) : 119 - 125
  • [2] Ruthenium (II) complexes in catalytic oxidation
    Aguirre, P
    Sariego, R
    Moya, SA
    JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (3-4) : 401 - 413
  • [3] ENANTIOSELECTIVE CATALYTIC EPOXIDATION OF STYRENES BY IODOSYLBENZENE USING CHIRAL RUTHENIUM(II) SCHIFF-BASE COMPLEXES
    KURESHY, RI
    KHAN, NH
    ABDI, SHR
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (02) : 117 - 122
  • [4] Controllable synthesis of mesoporous cobalt oxide for peroxide free catalytic epoxidation of alkenes under aerobic conditions
    Weerakkody, Chandima
    Biswas, Sourav
    Song, Wenqiao
    He, Junkai
    Wasalathanthri, Niluka
    Dissanayake, Shanka
    Kriz, David A.
    Dutta, Biswanath
    Suib, Steven L.
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 221 : 681 - 690
  • [5] RUTHENIUM(II) 2-(PHENYLAZO)PYRIDINE COMPLEXES AS EPOXIDATION CATALYSTS
    BARF, GA
    SHELDON, RA
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 98 (03) : 143 - 146
  • [6] EPOXIDATION OF CYCLOHEXENE CATALYZED BY COPPER(II) COMPLEXES UNDER MUKAIYAMAS CONDITIONS
    CORAIN, B
    TESSARI, A
    ZECCA, M
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 96 (01) : L9 - L10
  • [7] Catalytic epoxidation of stilbenes with non-peripherally alkyl substituted carbonyl ruthenium phthalocyanine complexes
    Enow, Charles A.
    Marais, Charlene
    Bezuidenhoudt, Barend C. B.
    JOURNAL OF PORPHYRINS AND PHTHALOCYANINES, 2012, 16 (04) : 403 - 412
  • [8] Catalytic Activity of Chloro and Triflate Manganese(II) Complexes in Epoxidation Reactions: Reusable Catalytic Systems for Alkene Epoxidation
    Rich, Jordi
    Manrique, Ester
    Molton, Florian
    Duboc, Carole
    Collomb, Marie-Noelle
    Rodriguez, Montserrat
    Romero, Isabel
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2014, (16) : 2663 - 2670
  • [9] Chiral Co(II) Metal-Organic Framework in the Heterogeneous Catalytic Oxidation of Alkenes under Aerobic and Anaerobic Conditions
    Tuci, Giulia
    Giambastiani, Giuliano
    Kwon, Stephanie
    Stair, Peter C.
    Snurr, Randall Q.
    Rossin, Andrea
    ACS CATALYSIS, 2014, 4 (03): : 1032 - 1039
  • [10] Synthesis and catalytic activity of ruthenium(II) complexes containing acetylacetonate
    Paul, BC
    Sarkhel, P
    Poddar, RK
    JOURNAL OF COORDINATION CHEMISTRY, 1995, 36 (04) : 267 - 272
12345