Zn vacancy induced room-temperature ferromagnetism in Mn-doped ZnO

被引:157
作者
Yan, Wensheng
Sun, Zhihu
Liu, Qinghua
Li, Zhongrui
Pan, Zhiyun
Wang, Jie
Wei, Shiqiang [1 ]
Wang, Dan
Zhou, Yingxue
Zhang, Xinyi
机构
[1] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Anhui, Peoples R China
[2] Fudan Univ, Dept Phys, Surface Phys Lab, Shanghai 200433, Peoples R China
[3] Fudan Univ, Synchrotron Radiat Res Ctr, Shanghai 200433, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1063/1.2769391
中图分类号
O59 [应用物理学];
学科分类号
摘要
X-ray absorption fine structure (XAFS) and first-principles calculations were employed to study the structure and ferromagnetism origin of Zn0.97Mn0.03O thin film grown by metal organic chemical vapor deposition. The magnetization measurements indicate that this sample is ferromagnetic at room temperature. The Mn ions are located at the substitutional Zn sites as revealed by the Mn K-edge XAFS spectroscopy. Moreover, the O K-edge XAFS analysis indicated the existence of numerous Zn vacancies. Based on first-principles calculations, the authors propose that the Zn vacancy can induce the room-temperature ferromagnetism in Mn-doped ZnO.
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页数:3
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共 24 条
[1]   Seeking room-temperature ferromagnetic semiconductors [J].
Ando, Koji .
SCIENCE, 2006, 312 (5782) :1883-1885
[2]   Real-space multiple-scattering calculation and interpretation of x-ray-absorption near-edge structure [J].
Ankudinov, AL ;
Ravel, B ;
Rehr, JJ ;
Conradson, SD .
PHYSICAL REVIEW B, 1998, 58 (12) :7565-7576
[3]   From ferromagnetic to antiferromagnetic interactions in n-type Zn1-xMnxO:: An electron paramagnetic resonance study [J].
Ben Mahmoud, A. ;
von Bardeleben, H. J. ;
Cantin, J. L. ;
Mauger, A. ;
Chikoidze, E. ;
Dumont, Y. .
PHYSICAL REVIEW B, 2006, 74 (11)
[4]   PROJECTOR AUGMENTED-WAVE METHOD [J].
BLOCHL, PE .
PHYSICAL REVIEW B, 1994, 50 (24) :17953-17979
[5]  
Chattopadhyay S, 2007, AIP CONF PROC, V882, P809
[6]   Donor impurity band exchange in dilute ferromagnetic oxides [J].
Coey, JMD ;
Venkatesan, M ;
Fitzgerald, CB .
NATURE MATERIALS, 2005, 4 (02) :173-179
[7]   Zener model description of ferromagnetism in zinc-blende magnetic semiconductors [J].
Dietl, T ;
Ohno, H ;
Matsukura, F ;
Cibert, J ;
Ferrand, D .
SCIENCE, 2000, 287 (5455) :1019-1022
[8]   Magnetic properties of mn-doped ZnO [J].
Fukumura, T ;
Jin, ZW ;
Kawasaki, M ;
Shono, T ;
Hasegawa, T ;
Koshihara, S ;
Koinuma, H .
APPLIED PHYSICS LETTERS, 2001, 78 (07) :958-960
[9]   Evidence of oxygen vacancy enhanced room-temperature ferromagnetism in Co-doped ZnO [J].
Hsu, H. S. ;
Huang, J. C. A. ;
Huang, Y. H. ;
Liao, Y. F. ;
Lin, M. Z. ;
Lee, C. H. ;
Lee, J. F. ;
Chen, S. F. ;
Lai, L. Y. ;
Liu, C. P. .
APPLIED PHYSICS LETTERS, 2006, 88 (24)
[10]   Ferromagnetism in Cu-doped ZnO from first-principles theory [J].
Huang, L. M. ;
Rosa, A. L. ;
Ahuja, R. .
PHYSICAL REVIEW B, 2006, 74 (07)