Rheotens mastercurves and elongational viscosity of polymer melts

被引:40
|
作者
Wagner, MH [1 ]
Collignon, B [1 ]
Verbeke, J [1 ]
机构
[1] UNIV CATHOLIQUE LOUVAIN,UNITE MECH APPL,B-1348 LOUVAIN,BELGIUM
关键词
polymer melts; melt spinning; Rheotens; mastercurve; elongational; viscosity;
D O I
10.1007/BF00396038
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
In a Rheotens experiment, the tensile force needed for elongation of an extruded filament is measured as a function of the draw ratio. For thermo-rheologically simple polymer melts, the existence of Rheotens-mastercurves was proved by Wagner, Schulze, and Gottfert (1995). Rheotens-mastercurves are invariant with respect to changes in melt temperature and changes in the average molar mass. By use of purely viscous models, we convert Rheotens-mastercurves of a branched and a linear polyethylene melt to elongational viscosity as a function of strain rate. The resulting elongational viscosity from constant force extension experiments is found to be in general agreement with what is expected as steady-state viscosity of polyethylene melts measured in either constant strain-rate or constant stress mode.
引用
收藏
页码:117 / 126
页数:10
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