Novel ferrocene-based nanoporous organic polymers for clean energy application

被引：52

作者：

Liu, Qingquan ^{[1
]}

Tang, Zhe ^{[1
]}

Wu, Minda ^{[1
]}

Liao, Bo ^{[1
]}

Zhou, Hu ^{[1
]}

Ou, Baoli ^{[1
]}

Yu, Guipeng ^{[2
]}

Zhou, Zhihua ^{[1
]}

Li, Xiaojuan ^{[1
]}

机构：

[1] Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Key Lab Theoret Chem & Mol Simulat, Minist Educ, Xiangtan 411201, Peoples R China

[2] Cent S Univ, Coll Chem & Chem Engn, Key Lab Resources Chem Nonferrous Met, Minist Educ, Changsha 410083, Hunan, Peoples R China

来源：

RSC ADVANCES | 2015年 / 5卷 / 12期

关键词：

CONJUGATED MICROPOROUS POLYMERS; GAS-STORAGE; LINKED POLYMERS; METHANE STORAGE; CARBON-DIOXIDE; CO2; ADSORPTION; NETWORKS; FRAMEWORKS; SEPARATION; HYDROGEN;

D O I：

10.1039/c4ra12834f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel ferrocene-based nanoporous organic polymer (FNOPs-1) for clean energy application has been prepared by coupling 1,1'-ferrocene-dicarboxaldehyde with melamine. The BET surface area and the total pore volume of FNOPs-1 are 752.4 m(2) g(-1) and 1.32 cm(3) g(-1), respectively. FNOPs-1 exhibits excellent gas storage capacities such as 16.61 wt% of carbon dioxide, 3.48 wt% of methane, and 1.27 wt% of hydrogen at 273 K/1.0 bar.

引用

页码：8933 / 8937

页数：5

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