Potassium hydroxide catalyst supported on palm shell activated carbon for transesterification of palm oil

被引:137
作者
Baroutian, Saeid [1 ]
Aroua, Mohamed Kheireddine [1 ]
Raman, Abdul Aziz Abdul [1 ]
Sulaiman, Nik Meriam Nik [1 ]
机构
[1] Univ Malaya, Fac Engn, Dept Chem Engn, Kuala Lumpur 50603, Malaysia
关键词
Biodiesel; Potassium hydroxide; Optimization; BIODIESEL PRODUCTION; SOYBEAN OIL; BASE CATALYST; RAPESEED OIL; OPTIMIZATION;
D O I
10.1016/j.fuproc.2010.05.009
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, potassium hydroxide catalyst supported on palm shell activated carbon was developed for transesterification of palm oil. The Central Composite Design (CCD) of the Response Surface Methodology (RSM) was employed to investigate the effects of reaction temperature, catalyst loading and methanol to oil molar ratio on the production of biodiesel using activated carbon supported catalyst. The highest yield was obtained at 64.1 degrees C reaction temperature, 30.3 wt.% catalyst loading and 24:1 methanol to oil molar ratio. The physical and chemical properties of the produced biodiesel met the standard specifications. This study proves that activated carbon supported potassium hydroxide is an effective catalyst for transesterification of palm oil. (c) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:1378 / 1385
页数:8
相关论文
共 31 条
[1]   Experimental evaluation of the transesterification of waste palm oil into biodiesel [J].
Al-Widyan, MI ;
Al-Shyoukh, AO .
BIORESOURCE TECHNOLOGY, 2002, 85 (03) :253-256
[2]  
American Society for Testing and Materials, 2007, D9307 ASTM
[3]  
Anderson M.J., 2007, DOE Simplified: practical tools for effective experimentation", V2nd
[4]  
Anderson MJ, 2005, OPT ENG MAG, P25
[5]  
[Anonymous], 1995, D250091 ASTM, V05
[6]  
[Anonymous], 2008, OIL WORLD STAT UPD, P15
[7]  
[Anonymous], 2003, EN14105
[8]  
[Anonymous], 2006, STANDARD TEST METHOD
[9]  
*ASTM, 2002, D576802 ASTM3
[10]  
*ASTM, 2003, D658407 ASTM