Recent progress and future challenges in the supramolecular polymerization of metal-containing monomers

被引:47
作者
Baeumer, Nils [1 ]
Matern, Jonas [1 ]
Fernandez, Gustavo [1 ]
机构
[1] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 36, D-48149 Munster, Germany
基金
欧洲研究理事会;
关键词
PI STACKING INTERACTIONS; PLATINUM COMPLEXES; MOLECULES; DRIVEN; DEPOLYMERIZATION; CRYSTALLIZATION; AMPLIFICATION; METALLOGELS; ASSEMBLIES; CATENANES;
D O I
10.1039/d1sc03388c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The self-assembly of discrete molecular entities into functional nanomaterials has become a major research area in the past decades. The library of investigated compounds has diversified significantly, while the field as a whole has matured. The incorporation of metal ions in the molecular design of the (supra-)molecular building blocks greatly expands the potential applications, while also offering a promising approach to control molecular recognition and attractive and/or repulsive intermolecular binding events. Hence, supramolecular polymerization of metal-containing monomers has emerged as a major research focus in the field. In this perspective article, we highlight recent significant advances in supramolecular polymerization of metal-containing monomers and discuss their implications for future research. Additionally, we also outline some major challenges that metallosupramolecular chemists (will) have to face to produce metallosupramolecular polymers (MSPs) with advanced applications and functionalities.
引用
收藏
页码:12248 / 12265
页数:18
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