Electrografting of diazonium salts: A kinetics study

被引：26
作者：
Bouden, Sarra [1 ]
Pinson, Jean [2 ]
Vautrin-Ul, Christine [1 ]
机构：
[1] Univ Orleans, CNRS, UMR7374, ICMN,Interfaces Confinement Mat & Nanostruct, 1b Rue Ferollerie, F-45071 Orleans 2, France
[2] Univ Paris Diderot, Sorbonne Paris Cite, ITODYS, UMR CNRS 7086, 15 Rue JA de Baif, F-75205 Paris 13, France
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 2017年 / 81卷
关键词：
Diazonium salts; Kinetics; EQCM; Substituents effects; ELECTROCHEMICAL REDUCTION; COVALENT MODIFICATION; ARYL GROUPS; IN-SITU; CARBON; SURFACE; GOLD; CHEMISTRY; FILMS; FABRICATION;
D O I：
10.1016/j.elecom.2017.06.007
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
The rates of electrochemical grafting of different diazonium salts on gold are measured by EQCM (Electrochemical Quartz Crystal Microbalance). These rates correlate reasonably well with the sigma(para) Hammett constant, indicating that the partial electrophilic character of the intermediate aryl radical favors attack on the gold surface.
引用
收藏
页码：120 / 123
页数：4
相关论文
共 36 条
[1]   Formation of polyphenylene films on metal electrodes by electrochemical reduction of benzenediazonium salts [J].
Adenier, A ;
Combellas, C ;
Kanoufi, F ;
Pinson, J ;
Podvorica, FI .
CHEMISTRY OF MATERIALS, 2006, 18 (08) :2021-2029
[2]   Covalent modification of carbon surfaces by aryl radicals generated from the electrochemical reduction of diazonium salts [J].
Allongue, P ;
Delamar, M ;
Desbat, B ;
Fagebaume, O ;
Hitmi, R ;
Pinson, J ;
Saveant, JM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (01) :201-207
[3]   Advances on the use of diazonium chemistry for functionalization of materials used in energy storage systems [J].
Assresahegn, Birhanu Desalegn ;
Brousse, Thierry ;
Belanger, Daniel .
CARBON, 2015, 92 :362-381
[4]   Electrografting: a powerful method for surface modification [J].
Belanger, Daniel ;
Pinson, Jean .
CHEMICAL SOCIETY REVIEWS, 2011, 40 (07) :3995-4048
[5]   Evidence for covalent bonding of aryl groups to MnO2 nanorods from diazonium-based grafting [J].
Bell, K. J. ;
Brooksby, P. A. ;
Polson, M. I. J. ;
Downard, A. J. .
CHEMICAL COMMUNICATIONS, 2014, 50 (89) :13687-13690
[6]  
BELMONT JA, Patent No. 5554739
[7]   Electro-reduction of diazonium salts on gold:: Why do we observe multi-peaks? [J].
Benedetto, Alessandro ;
Balog, Mirela ;
Viel, Pascal ;
Le Derf, Franck ;
Salle, Marc ;
Palacin, Serge .
ELECTROCHIMICA ACTA, 2008, 53 (24) :7117-7122
[8]  
Berisha A, 2016, ELECTROANAL CHEM, V26, P115
[9]   Organic layers bonded to industrial, coinage, and noble metals through electrochemical reduction of aryldiazonium salts [J].
Bernard, MC ;
Chaussé, A ;
Cabet-Deliry, E ;
Chehimi, MM ;
Pinson, J ;
Podvorica, F ;
Vautrin-Ul, C .
CHEMISTRY OF MATERIALS, 2003, 15 (18) :3450-3462
[10]   Correlations between the grafting conditions and the copper detection by diazonium functionalized carbon screen-printed electrodes [J].
Bouden, Sarra ;
Bellakhal, Nizar ;
Chausse, Annie ;
Dachraoui, Mohamed ;
Vautrin-Ul, Christine .
ELECTROCHIMICA ACTA, 2014, 125 :149-155
1234