Synthesis, Optoelectronic and Self-Assembly Properties of Diazadioxaacene Derivatives

被引：19

作者：

Pan, Huahang ^{[1
]}

Duan, Jingdan ^{[1
]}

Zhai, Guixia ^{[1
]}

Jin, Pengcheng ^{[1
]}

Zhao, Xiaohui ^{[2
]}

Jiang, Li ^{[3
]}

Xiao, Jinchong ^{[1
]}

机构：

[1] Hebei Univ, Key Lab Chem Biol Hebei Prov, Coll Chem & Environm Sci, Baoding 071002, Peoples R China

[2] Hebei Univ, Coll Phys Sci & Technol, Baoding 071002, Peoples R China

[3] Inst Chem, Beijing Natl Lab Mol Sci, Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2017年 / 12卷 / 16期

基金：

中国国家自然科学基金;

关键词：

diazadioxaacene; physical property; self-assembly; single crystal; synthesis; MEMORY DEVICE APPLICATION; PHYSICAL-PROPERTIES; AQUEOUS-SOLUTION; BUILDING-BLOCKS; TWISTED ACENES; PI-GELATORS; AZAACENES; BEHAVIOR; NANOPARTICLES; HETEROACENES;

D O I：

10.1002/asia.201700700

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel diazadioxaacene derivatives (ADOP and ADOQ) have been successfully synthesized and characterized. Their single crystal analyses disclose that molecule ADOP forms a twisted topology configuration, whereas ADOQ adopts reclining-chair architecture. Both of them emit strong blue fluorescence in organic solvents. Moreover, they can self-assemble to form regular nanobelts and nanowires, respectively, via a simple surfactant-assisted method.

引用

页码：2121 / 2126

页数：6

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