Synthesis of tunable bisphosphine ligands and their application in asymmetric hydrogenation of quinolines

被引：100
|
作者：
Wang, Xiao-Bing [1 ]
Zhou, Yong-Gui [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 14期
关键词：
D O I：
10.1021/jo800779r
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A series of tunable axial chiral bisphosphine ligands have been synthesized from (S)-MeO-Biphep. The Ir complex of the MeO-PEG-supported ligand (S)-4k has been successfully applied in asymmetric hydrogenation of quinolines with up to 92% ee. The catalyst system is air-stable and recyclable.
引用
收藏
页码：5640 / 5642
页数：3
相关论文
共 50 条
  • [21] Synthesis of A Series of Tridentate Ligands with Ferrocene Framework and Their Application in Asymmetric Hydrogenation of Iridium
    Lin, Xin
    Guan, Fanfu
    Wen, Jialin
    Shao, Pan-Lin
    Zhang, Xumu
    PROGRESS IN CHEMISTRY, 2020, 32 (11) : 1680 - 1696
  • [22] The synthesis of spirobitetraline phosphoramidite ligands and their application in rhodium-catalyzed asymmetric hydrogenation
    Huo, Xiang-Hong
    Xie, Jian-Hua
    Wang, Qiu-Shi
    Zhou, Qi-Lin
    ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (16) : 2477 - 2484
  • [23] Chiral pyrophosphites -: synthesis and application as ligands in Rh(I)-catalyzed asymmetric hydrogenation
    Korostylev, A
    Selent, D
    Monsees, A
    Borgmann, C
    Börner, A
    TETRAHEDRON-ASYMMETRY, 2003, 14 (13) : 1905 - 1909
  • [24] Asymmetric hydrogenation of quinolines catalyzed by iridium with chiral ferrocenyloxazoline derived N,P ligands
    Lu, SM
    Han, XW
    Zhou, YG
    ADVANCED SYNTHESIS & CATALYSIS, 2004, 346 (08) : 909 - 912
  • [25] New chiral aminophosphine carboxyphosphinite ligands (AMPCP). Synthesis and application in asymmetric hydrogenation and hydroformylation
    Naili, S
    Mortreux, A
    Agbossou, F
    TETRAHEDRON-ASYMMETRY, 1998, 9 (19) : 3421 - 3430
  • [26] New ionic phosphite ligands: synthesis and application in asymmetric Rh-catalyzed hydrogenation
    Lyubimov, S. E.
    Petrovskii, P. V.
    Davankov, V. A.
    RUSSIAN CHEMICAL BULLETIN, 2009, 58 (03) : 528 - 531
  • [27] New ionic phosphite ligands: synthesis and application in asymmetric Rh-catalyzed hydrogenation
    S. E. Lyubimov
    P. V. Petrovskii
    V. A. Davankov
    Russian Chemical Bulletin, 2009, 58 : 528 - 531
  • [28] Synthesis of dendritic BINAP ligands and their applications in asymmetric hydrogenation
    Deng, GJ
    Fan, QH
    Chen, XM
    CHINESE JOURNAL OF CHEMISTRY, 2002, 20 (11) : 1139 - 1141
  • [29] Application of ferrocene-derived chiral S,P-donor ligands for iridium-catalyzed asymmetric hydrogenation of quinolines
    Zhao, YJ
    Wang, YQ
    Zhou, YG
    CHINESE JOURNAL OF CATALYSIS, 2005, 26 (09) : 737 - 739
  • [30] Synthesis of Dendritic BINAP Ligands and Their Applications in Asymmetric Hydrogenation
    邓国军
    范青华
    陈晓闽
    Chinese Journal of Chemistry, 2002, (11) : 1139 - 1141
12345